Chemical Fixation of Carbon Dioxide Catalyzed by Bimetallic Aluminum(Salen) Complex

2012 ◽  
Vol 549 ◽  
pp. 406-410 ◽  
Author(s):  
Zhen Xiao Duan ◽  
Tao Fang ◽  
Min Wang ◽  
Guo Zhi Fan
Keyword(s):  
Carbon Dioxide ◽  
Carbon Tetrachloride ◽  
Lewis Acid ◽  
Chemical Fixation ◽  
Bimetallic Complex ◽  
Reaction Conditions ◽  
Salen Complex ◽  
Salen Complexes ◽  
Excellent Activity ◽  
Fixation Of Carbon Dioxide

Bimetallic aluminum(salen) complexes were prepared and used as catalyst for the synthesis of DPC from CO2 and phenol in the presence of carbon tetrachloride. The bimetallic complex derived from 3,5-ditert salicylaldehyde and 1,2-cyclohexanediamine revealed more excellent activity than that obtained in the presence of other complexes and the simple Lewis acid ZnCl2. The influence of the amount of complex and the reaction conditions including the pressure of CO2 and the reaction temperature was also investigated.

Titanate nanotube-promoted chemical fixation of carbon dioxide to cyclic carbonate: a combined experimental and computational study

2016 ◽  
Vol 6 (3) ◽  
pp. 780-790 ◽  
Author(s):  
Aibing Chen ◽  
Tiancong Zhao ◽  
Hui Gao ◽  
Limin Chen ◽  
Jinzhu Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Lewis Acid ◽  
Computational Study ◽  
Cyclic Carbonate ◽  
Titanate Nanotubes ◽  
Acid Catalysts ◽  
Chemical Fixation ◽  
Lewis Acid Catalysts ◽  
Titanate Nanotube ◽  
Fixation Of Carbon Dioxide

Titanate nanotubes are efficiently used as air- and water-tolerant, and recyclable Lewis acid catalysts for CO2 fixation to cyclic carbonate.

N-Heterocyclic carbene functionalized MCM-41 as an efficient catalyst for chemical fixation of carbon dioxide

2011 ◽  
Vol 13 (3) ◽  
pp. 644 ◽  
Author(s):  
Hui Zhou ◽  
Yi-Ming Wang ◽  
Wen-Zhen Zhang ◽  
Jing-Ping Qu ◽  
Xiao-Bing Lu
Keyword(s):  
Carbon Dioxide ◽  
Chemical Fixation ◽  
Efficient Catalyst ◽  
Fixation Of Carbon Dioxide ◽  
Mcm 41

Bifunctional Aluminum Catalysts for the Chemical Fixation of Carbon Dioxide into Cyclic Carbonates

2018 ◽  
Vol 6 (4) ◽  
pp. 5322-5332 ◽  
Author(s):  
Felipe de la Cruz-Martínez ◽  
Javier Martínez ◽  
Miguel A. Gaona ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Fixation Of Carbon Dioxide
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