Determination of Boric Anhydride in Ascharite Ores by Inductively Coupled Plasma Atomic Emission Spectrometry

2013 ◽  
Vol 652-654 ◽  
pp. 1445-1449
Author(s):  
Xiang Dong Wen ◽  
Shi Hua Chen ◽  
Mei Shao
Keyword(s):  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Spectral Lines ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission ◽  
Plasma Atomic Emission Spectrometry ◽  
Boric Anhydride ◽  
Inductively Coupled ◽  
Relative Standard

Inductively coupled plasma atomic emission spectroscopy was applied to the determination of boric anhydride in ascharite ores. Pretreatment method, reagents used for acid decomposition and the interferences from matrix and coexistent elements were discussed in details respectively. The analytical spectral lines were selected while experimental parameters were optimized. The results indicated that after the samples were completely dissolved and collected with hydrochloric acid (1+1) in a sealed container with a reflux condenser by the low-temperature heating method, they could be directly analyzed and determined with ICP-AES at optimized operating parameters. The relative standard deviation of the method is less than 1.4% within the measurement range of 0.1% ~ 40% and the recovery rate is in the range of 98.1% ~ 101.0%. The method was proved satisfactory with wide linear range, low detection limit and also high sensitivity and accuracy.

Determination of Al, Cu, Ni in Zr-Based Amorphous Alloy by Inductively Coupled Plasma Atomic Emission Spectrometry

2015 ◽  
Vol 1095 ◽  
pp. 218-221
Author(s):  
Lan Ma ◽  
Guang He Qin ◽  
Qiong Yu ◽  
Jing Zhou
Keyword(s):  
Amorphous Alloy ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Spectral Lines ◽  
Atomic Emission Spectrometry ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission ◽  
Plasma Atomic Emission Spectrometry ◽  
Inductively Coupled

A Method was studied for the determination of Al、Cu、Ni in Zr-based amorphous alloy by inductively coupled plasma atomic emission spectrometry (ICP-AES). Samples were dissolved by hydrochloric acid,nitric acid and hydrofluoric acid,analytical spectral lines for aluminum,copper,nickle are 308.215nm,327.396nm and 231.604nm.Interference of zinc was eliminated by the matrix-matching method, the experiments were done with optimized Operating Parameters. The correlation coefficients of the calibration curve are all 0.999,detection limits are 0.0010%,0.005% and 0.0006% respectively,and the range of recovery is 98%-104%.

Determination of Metal Elements in Maca from Different Areas by Inductively Coupled Plasma-Atomic Emission Spectrometry

2014 ◽  
Vol 978 ◽  
pp. 19-22 ◽  
Author(s):  
Hong Bo Han ◽  
Qin Dong ◽  
Yi Diao ◽  
Hui Ping Wei ◽  
Min Jie Li
Keyword(s):  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Atomic Emission Spectrometry ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission ◽  
Plasma Atomic Emission Spectrometry ◽  
Metal Elements ◽  
Inductively Coupled ◽  
Relative Standard

In this paper, the contents of these elements including Cu, Fe, Mn, Zn, Al, Cd, Pb, Ti and As were determined by ICP-AES technique, which elements originated from maca from different places. Detection limits ranged 0.0022 ug/ml-1 and 0.077ug/ml-1, the relative standard deviations for all these elements were lower than 2%, and recovery rates ranged 95.56% and 106.2%. The results showed that there were rich metal elements in maca from different places; contents of Fe and Al were highest; contents of Mn, Zn, Cu and Ti were moderately high, and contents of As, Cd and Pb were lowest. Futhermore, Cu, Fe, Mn, Zn were essential to people’s health, and Al, Cd, As, Pb and Ti had potentially physiologically toxic. Finally, concentrations of elements within macafrom different places were different, which may have some relations with the environment where maca grew. As a result, the determining method which elements of maca. are determined by ICP-AES is rapid, accurate and convenient, and wild macamay contain toxic elements because of pollutional soil and environment, so macacultivated artificially can effectively reduce harmful elements.

scholarly journals Determination of Nine Elements in Sherry Wine by Inductively Coupled Plasma-Atomic Emission Spectrometry

1996 ◽  
Vol 79 (5) ◽  
pp. 1191-1197 ◽  
Author(s):  
Miguel lópez-Artíguez ◽  
Ana M Camean ◽  
Manuel Repetto
Keyword(s):  
Inductively Coupled Plasma ◽  
Absorption Spectrometry ◽  
Atomic Emission ◽  
Atomic Emission Spectrometry ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission ◽  
Plasma Atomic Emission Spectrometry ◽  
Inductively Coupled ◽  
Relative Standard

Abstract A quick and simple method was developed to analyze various "fino" sherry wines for routine determination of Al, Ca, Cu, Fe, K, Mg, Mn, Na, and Zn content. The analysis involved heating the wine sample in an oven at 80°C to evaporate the ethanol, followed by sequential determination of the elements by inductively coupled plasma-atomic emission spectrometry. The following metal concentrations (mg/L) were obtained: Al, 1.02-4.06; Ca, 85.00-150.00; Cu, 0.06-1.62; Fe, 2.19-4.91; K, 435.02-651.65; Mg, 79.1-108.57; Mn, 0.37-2.13; Na, 27.09-54.26; and Zn, 0.12-5.08. Mean recoveries of elements from fortified wines were 101.6% for Al, 103.6% for Ca, 97.4% for Cu, 100.3% for Fe, 100.7% for K, 103.6% for Mg, 99.1% for Mn, 105.7% for Na, and 99.99% for Zn. The estimated detection limits were 15.2 μg Al/L, 39.9 μg Ca/L, 20.1 μg Cu/L, 19.1 μg Fe/L, 116.4 μg K/L, 20.3 μg Mg/L, 20.2 μg Mn/L, 34.6 μg Na/L, and 25.4 μg Zn/L. The repeatability relative standard deviation ranged from 1.1 (Mg) to 5.3% (Na), and the reproducibility relative standard deviation ranged from 2.0 (Mg) to 9.3% (Al). The results were compared with those obtained y flame atomic absorption spectrometry and, for Al, by graphite furnace atomic absorption spectrometry. By the method for regression lines we demonstrated that no differences in concentrations were obtained for any of the elements assayed. The proposed method is rapid and simple, needs only a small amount of sample, and has acceptable analytical characteristics.

Determination of Iridium in Platinum Jewelry Alloys by ICP-AES

2011 ◽  
Vol 79 ◽  
pp. 248-253 ◽  
Author(s):  
Rui Feng Gao ◽  
Yuan Yuan Du ◽  
Pei Yang
Keyword(s):  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Atomic Emission Spectrometry ◽  
Emission Spectrometry ◽  
Analytical Line ◽  
Plasma Atomic Emission ◽  
Plasma Atomic Emission Spectrometry ◽  
Inductively Coupled ◽  
Relative Standard

A method for the determination of iridium impurity in platinum jewelry alloys by inductively coupled plasma atomic emission spectrometry (ICP-AES) was reported. Spectral interferences of Au, Cr, Cu, Fe, Ni and Pt to Ir at specific wavelengths have been investigated. The spectral coincidence profiles were recorded and interfering lines were identified. The optimum analytical line of 38 iridium emission lines was 215.268 nm {156}. Ir 212.681 {158} and Ir 205.116 nm {164} can be used as analytical lines after rectified by Inter-Element Corrections (IEC) coefficients. Ir 186.250 nm is a new candidate analytical line. Ir 224.268 nm is not being recommended by reason of the severe spectral interference from Cu and Ni. Ir 322.08 nm is not being recommended for its weaker emission intensity. Validation was performed in terms of detection limits, linearity, precision and recovery. The relative standard deviations (RSD) and recoveries of the method are in the range of 0.59%~1.84% and 85.5%~93.2%, respectively.

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