Martensitic Transformation Behavior and Shape Memory Effect of an Aged Ni-rich Ti-Ni-Hf High Temperature Shape Memory Alloy

2008 ◽  
Vol 138 ◽  
pp. 399-406 ◽  
Author(s):  
Xiang Long Meng ◽  
Yu Dong Fu ◽  
Wei Cai ◽  
J.X. Zhang ◽  
Qing Fen Li ◽  
...  

The martensitic transformation behavior and shape memory effect (SME) have been investigated in a Ni-rich Ti29.6Ni50.4Hf20 high temperature shape memory alloy (SMA) in the present study. After aging, the transformation temperatures of Ti29.6Ni50.4Hf20 alloy increase obviously due to the precipitation of (Ti,Hf)3Ni4 particles. And the transformation sequence changes from one-step to two-step. When the experimental alloy is aged at different temperatures for 2h, the transformation temperatures increase rapidly with increasing the aging temperature and then change slightly with further increasing the aging temperature. Most of the martensite variants preferentially oriented in the aged Ti29.6Ni50.4Hf20 alloy. The aged Ti29.6Ni50.4Hf20 alloy shows the better thermal stability of transformation temperatures than the solution-treated one because the precipitates depress the introduction of defects during thermal cycling. In addition, the proper aged Ti29.6Ni50.4Hf20 alloy also shows the larger SME than the solution-treated one since the precipitates strengthen the matrix strongly.

2006 ◽  
Vol 41 (18) ◽  
pp. 6165-6167 ◽  
Author(s):  
Z. Y. Gao ◽  
Y. Wu ◽  
Y. X. Tong ◽  
W. Cai ◽  
Y. F. Zheng ◽  
...  

2013 ◽  
Vol 738-739 ◽  
pp. 195-199 ◽  
Author(s):  
Philippe Vermaut ◽  
Anna Manzoni ◽  
Anne Denquin ◽  
Frédéric Prima ◽  
Richard Portier

Among the different systems for high temperature shape memory alloys (SMA’s), equiatomic RuNb and RuTa alloys demonstrate both shape memory effect (SME) and MT temperatures above 800°C. Equiatomic compounds undergo two successive martensitic transformations, β (B2) → β’ (tetragonal) → β’’ (monoclinic), whereas out of stoechiometry alloys exhibit a single transition from cubic to tetragonal. In the case of two successive martensitic transformations, we expect to have a finer microstructure of the second martensite because it is supposed to develop inside the smallest twin elements of the former one. In equiatomic Ru-based alloys, if the first martensitic transformation is “normal”, the second one gives different unexpected microstructures with, for instance, twins with a thickness which is larger than the smallest spacing between twin variants of the first martensite. In fact, the reason for this unexpected hierarchy of the twins size is that the second martensitic transformation takes place in special conditions: geometrically, elastically and crystallographically constrained.


2019 ◽  
Vol 163 ◽  
pp. 1-13 ◽  
Author(s):  
C. Hayrettin ◽  
O. Karakoc ◽  
I. Karaman ◽  
J.H. Mabe ◽  
R. Santamarta ◽  
...  

2013 ◽  
Vol 58 (6) ◽  
pp. 878-887 ◽  
Author(s):  
V. G. Pushin ◽  
N. N. Kuranova ◽  
E. B. Marchenkova ◽  
E. S. Belosludtseva ◽  
V. A. Kazantsev ◽  
...  

2010 ◽  
Vol 654-656 ◽  
pp. 2150-2153 ◽  
Author(s):  
Hideki Hosoda ◽  
Makoto Taniguchi ◽  
Tomonari Inamura ◽  
Hiroyasu Kanetaka ◽  
Shuichi Miyazaki

Effects of single- and multi-step aging on mechanical properties and shape memory properties of Ti-6Mo-8Al (mol%) biomedical shape memory alloy were studied using tensile tests at room temperature (RT). The solution-treated alloy at RT was two phase of bcc β and martensite α". Tensile tests revealed that the solution-treated alloy exhibited good shape memory effect. As for the single-step aging, (1) pseudoelastic shape recovery by unloading was observed after aging at 623K, (2) the alloy became brittle after aging at 773K due to ω embrittlement, and (3) strength was improved with small shape memory effect by aging at 1023K. On the other hand, after a multistep aging at 773K-1023K-1123K, the alloy was strengthened and showed perfect shape recovery. The improvement must be achieved by the formation of fine and uniform hcp α precipitates.


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