scholarly journals Synthesis of Cyclometallated Pt(II) Complexes of a Bulky Bipyridine Ligand

OUSL Journal ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 27
Author(s):  
Sarath D. Perera
Keyword(s):  
Bipyridine Ligand

scholarly journals Iridium Complex Catalyzed Hydrogen Production from Glucose and Various Monosaccharides

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 891
Author(s):  
Ken-ichi Fujita ◽  
Takayoshi Inoue ◽  
Toshiki Tanaka ◽  
Jaeyoung Jeong ◽  
Shohichi Furukawa ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Catalytic System ◽  
Catalytic Reaction ◽  
Hydrogen Gas ◽  
Water Soluble ◽  
Starting Material ◽  
Iridium Complex ◽  
Production Of Hydrogen ◽  
Bipyridine Ligand

A new catalytic system has been developed for hydrogen production from various monosaccharides, mainly glucose, as a starting material under reflux conditions in water in the presence of a water-soluble dicationic iridium complex bearing a functional bipyridine ligand. For example, the reaction of D-glucose in water under reflux for 20 h in the presence of [Cp*Ir(6,6′-dihydroxy-2,2′-bipyridine)(H2O)][OTf]2 (1.0 mol %) (Cp*: pentamethylcyclopentadienyl, OTf: trifluoromethanesulfonate) resulted in the production of hydrogen gas in 95% yield. In the present catalytic reaction, it was experimentally suggested that dehydrogenation of the alcoholic moiety at 1-position of glucose proceeded.

scholarly journals Self-assembled luminescent Cu(I) tetrametallic metallacycles based on 3,3’-bipyridine ligand

2021 ◽  
Author(s):  
Christophe Lescop ◽  
Guillaume Calvez ◽  
Florent Moutier ◽  
Jana Schiller
Keyword(s):  
Supramolecular Chemistry ◽  
Bipyridine Ligand ◽  
Self Assembled

3,3’-bipyridine ligand B was reacted with pre-assembled [Cu2(2-dppm)2] Cu(I) bimetallic flexible precursor A accordingly to coordination-driven supramolecular chemistry synthetic principles. Outcomes obtained revealed the necessity to formally introduce bridging halide...

Synthesis, X-ray Studies and Magnetic Properties of Dinuclear NiII and CuII Complexes Bridged by the Azo-2,2′-bipyridine Ligand

2003 ◽  
Vol 2003 (5) ◽  
pp. 988-994 ◽  
Author(s):  
Cristian S. Campos-Fernández ◽  
José R. Galán-Mascarós ◽  
Bradley W. Smucker ◽  
Kim R. Dunbar
Keyword(s):  
Magnetic Properties ◽  
X Ray ◽  
Bipyridine Ligand

ChemInform Abstract: New Chiral Bis(oxazolinyl)bipyridine Ligand (Bipymox): Enantioselection in the Asymmetric Hydrosilylation of Ketones.

ChemInform ◽  
2010 ◽  
Vol 24 (21) ◽  
pp. no-no
Author(s):  
H. NISHIYAMA ◽  
S. YAMAGUCHI ◽  
S.-B. PARK ◽  
K. ITOH
Keyword(s):  
Bipyridine Ligand

scholarly journals (2,2′-Bipyridine-κ2 N,N′)(pyridine-2,6-dicarboxylato-κ2 N,O)palladium(II) monohydrate

IUCrData ◽  
2019 ◽  
Vol 4 (12) ◽  
Author(s):  
Kwang Ha
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Title Compound ◽  
Coordination Geometry ◽  
Intermolecular Hydrogen Bonds ◽  
Complex Molecules ◽  
Solvent Water Molecule ◽  
Solvent Water ◽  
Square Planar ◽  
Bipyridine Ligand

In the title compound, [Pd(C7H3NO4)(C10H8N2)]·H2O, the PdII cation is four-coordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,2′-bipyridine ligand, one O atom and one N atom from the pyridine-2,6-dicarboxylate anion. The complex and solvent water molecule are linked by intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis.

scholarly journals catena-Poly[[[bis(acetonitrile-κN)(4,4′-dimethoxy-2,2′-bipyridine-κ2 N,N′)copper(II)]-μ-trifluoromethanesulfonato-κ2 O:O′] trifluoromethanesulfonate]

IUCrData ◽  
2020 ◽  
Vol 5 (10) ◽  
Author(s):  
Rafael A. Adrian ◽  
Diego R. Hernandez ◽  
Hadi D. Arman
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Metal Organic Frameworks ◽  
Starting Material ◽  
Compound A ◽  
Distorted Octahedral ◽  
Weak Hydrogen Bonds ◽  
Polymeric Chains ◽  
Metal Organic ◽  
Bipyridine Ligand

The central copper(II) atom of the title salt, {[Cu(CF3SO3)(CH3CN)2(C12H12N2O2)](CF3SO3)} n or [[Cu(CH3CN)2(diOMe-bpy)(CF3SO3)](CF3SO3)] n where diOMe-bpy is 4,4′-dimethoxy-2,2′-bipyridine, C12H12N2O2, is sixfold coordinated by the N atoms of the chelating bipyridine ligand, the N atoms of two acetonitrile molecules, and two trifluoromethanesulfonate O atoms in a tetragonally distorted octahedral shape. The formation of polymeric chains [Cu(CH3CN)2(diOMe-bpy)(CF3SO3)]+ n leaves voids for the non-coordinating trifluoromethanesulfonate anions that interact with the complex through weak hydrogen bonds. The presence of weakly coordinating ligands like acetonitrile and trifluoromethanesulfonate makes the title compound a convenient starting material for the synthesis of novel metal–organic frameworks.

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