Stress Corrosion Cracking Behavior of Uranium Alloys

The stress corrosion cracking (SCC) behavior of U-3/4% Ti, and uranium alloys 3/4% Quad, 1% Quad, and 1% Quint have been studied utilizing a linear elastic fracture mechanics approach. The threshold stress intensities for stress corrosion crack propagation for these alloys have been determined in distilled H2O and NaCl solutions containing 50 ppm Cl− and 21,000 ppm Cl−. All of the alloys studied may be classified as very susceptible to SCC in aqueous solutions since they exhibit SCC in distilled H2O (<1 ppm Cl−) and have low KIscc values in NaCl solutions. Crack extension in all of the alloys in all environments was transgranular and failure occurred by brittle quasicleavage fracture in NaCl solution.