scholarly journals Nucleophilic Substitution Reactions of Y-Substituted-Phenyl Benzoates with Potassium Ethoxide in Anhydrous Ethanol: Reaction Mechanism and Role of K+Ion

2014 ◽  
Vol 35 (1) ◽  
pp. 177-181 ◽  
Author(s):  
Song-I Kim ◽  
Hyo-Jin Cho ◽  
Ik-Hwan Um
Keyword(s):  
Reaction Mechanism ◽  
Nucleophilic Substitution ◽  
Anhydrous Ethanol ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions

Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids

2014 ◽  
Vol 38 (6) ◽  
pp. 2611-2618 ◽  
Author(s):  
Marcela Gazitúa ◽  
Ricardo A. Tapia ◽  
Renato Contreras ◽  
Paola R. Campodónico
Keyword(s):  
Ionic Liquids ◽  
Reaction Mechanism ◽  
Nucleophilic Substitution ◽  
Substitution Reactions ◽  
Aromatic Nucleophilic Substitution ◽  
Solvation Effects ◽  
Nucleophilic Substitution Reactions

Solvation effects on the reaction mechanism for nucleophilic substitution reactions have been kinetically evaluated in conventional solvents and ionic liquids.

Investigating the role of halogen-bonded complexes in microsolvated Y−(H2O)n + CH3I SN2 reactions

2021 ◽  
Author(s):  
Xiaoyan Ji ◽  
Chongyang Zhao ◽  
Jing Xie
Keyword(s):  
Nucleophilic Substitution ◽  
Back Side ◽  
Front Side ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions ◽  
Sn2 Reactions ◽  
Bonded Complexes

A halogen-bonded complex pathway is computed for Y−(H2O)n + CH3I (Y = HO, F, Cl, Br, and I) ion–molecule nucleophilic substitution reactions and is compared with back-side and front-side attack pathways.

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