Investigating the role of halogen-bonded complexes in microsolvated Y−(H2O)n + CH3I SN2 reactions

Back Side ◽

Front Side ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions ◽

Sn2 Reactions ◽

Bonded Complexes

A halogen-bonded complex pathway is computed for Y−(H2O)n + CH3I (Y = HO, F, Cl, Br, and I) ion–molecule nucleophilic substitution reactions and is compared with back-side and front-side attack pathways.

ChemInform Abstract: NUCLEOPHILIC SUBSTITUTION REACTIONS OF N-ALKYLDI(TRIFLUOROMETHANE)SULFONIMIDES. ROLE OF THE SOLVENT HEXAMETHYLPHOSPHORIC TRIAMIDE

Chemischer Informationsdienst ◽

10.1002/chin.197843075 ◽

1978 ◽

Vol 9 (43) ◽

Author(s):

R. S. GLASS ◽

R. J. SWEDO

Keyword(s):

Substitution Reactions ◽

Hexamethylphosphoric Triamide ◽

The Role of Meisenheimer Complexes in Aromatic Nucleophilic Substitution Reactions

Techniques and Applications of Fast Reactions in Solution ◽

10.1007/978-94-009-9490-4_66 ◽

1979 ◽

pp. 469-472

Author(s):

Roger Bird

Keyword(s):

Substitution Reactions ◽

Aromatic Nucleophilic Substitution ◽

Nucleophilic Substitution Reactions ◽

Meisenheimer Complexes

Nucleophilic Substitution Reactions of Y-Substituted-Phenyl Benzoates with Potassium Ethoxide in Anhydrous Ethanol: Reaction Mechanism and Role of K+Ion

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2014.35.1.177 ◽

2014 ◽

Vol 35 (1) ◽

pp. 177-181 ◽

Cited By ~ 4

Author(s):

Song-I Kim ◽

Hyo-Jin Cho ◽

Ik-Hwan Um

Keyword(s):

Reaction Mechanism ◽

Anhydrous Ethanol ◽

Substitution Reactions ◽

Role of charge transfer in nucleophilic substitution reactions in clusters of 1-fluoro-n-chlorobenzene cations with ammonia molecules

The Journal of Physical Chemistry ◽

10.1021/j100188a015 ◽

1992 ◽

Vol 96 (9) ◽

pp. 3626-3632 ◽

Cited By ~ 24

Author(s):

C. Riehn ◽

C. Lahmann ◽

B. Brutschy

Keyword(s):

Charge Transfer ◽

Substitution Reactions ◽

ChemInform Abstract: Isotope Effects in Nucleophilic Substitution Reactions. Part 6. The Effect of Ion Pairing on the Transition State Structure of SN2 Reactions

ChemInform ◽

10.1002/chin.198846077 ◽

1988 ◽

Vol 19 (46) ◽

Author(s):

K. C. WESTAWAY ◽

Z. LAI

Keyword(s):

Transition State ◽

Isotope Effects ◽

Ion Pairing ◽

State Structure ◽

Transition State Structure ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions ◽

Sn2 Reactions

Nucleophilic substitution reactions of N-alkyldi(trifluoromethane)sulfonimides. Role of the solvent hexamethylphosphoric triamide

The Journal of Organic Chemistry ◽

10.1021/jo00405a048 ◽

1978 ◽

Vol 43 (11) ◽

pp. 2291-2294 ◽

Cited By ~ 15

Author(s):

Richard S. Glass ◽

Raymond J. Swedo

Keyword(s):

Substitution Reactions ◽

Hexamethylphosphoric Triamide ◽

Kinetic Study on Nucleophilic Substitution Reactions of 4-Nitrophenyl X-Substituted-Benzoates with Potassium Ethoxide: Reaction Mechanism and Role of K+Ion

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2014.35.1.225 ◽

2014 ◽

Vol 35 (1) ◽

pp. 225-230 ◽

Cited By ~ 4

Author(s):

Song-I Kim ◽

Min-Young Kim ◽

Ik-Hwan Um

Keyword(s):

Reaction Mechanism ◽

Kinetic Study ◽

Substitution Reactions ◽

Stereocontrol in Nucleophilic Substitution Reactions at Silicon: The Role of Permutation in Generating Silicon-Centered Chirality

Journal of the American Chemical Society ◽

10.1021/jacs.5b00861 ◽

2015 ◽

Vol 137 (13) ◽

pp. 4304-4307 ◽

Cited By ~ 24

Author(s):

Jonathan O. Bauer ◽

Carsten Strohmann

Keyword(s):

Substitution Reactions ◽

Synthesis of Diastereomeric Pyrrolidine Sulfamides via Anchimerically Assisted Nucleophilic Substitution Reactions

Letters in Organic Chemistry ◽

10.2174/1570178615666180110162202 ◽

2018 ◽

Vol 15 (5) ◽

pp. 352-358

Author(s):

Jorge Vargas-Caporali ◽

Arie van der Lee ◽

Georges Dewynter ◽

Eusebio Juaristi

Keyword(s):

Substitution Reactions ◽

The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH2CH2O)3-3,3′,3′′-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]

Dalton Transactions ◽

10.1039/d0dt03857a ◽

2021 ◽

Vol 50 (7) ◽

pp. 2671-2688

Author(s):

Marina Yu. Stogniy ◽

Sergey A. Anufriev ◽

Akim V. Shmal'ko ◽

Sergey M. Antropov ◽

Aleksei A. Anisimov ◽

...

Keyword(s):

Substitution Reactions ◽

An unusual reactivity of 9-iodo-nido-carborane [9-I-7,8-C2B9H11]− towards nucleophiles under strong basic conditions was revealed.