Measurement Of Refractive Indices Of Ternary Mixtures Using Digital Interferometry And Multi-Wavelength Abbemat Refractometer

Author(s):  
Mohammed Yahya
1947 ◽  
Vol 25b (3) ◽  
pp. 228-242 ◽  
Author(s):  
A. N. Campbell ◽  
S. I. Miller

The densities and refractive indices (Nc) of binary and ternary mixtures of benzene, ethyl alcohol, and carbon tetrachloride have been determined at 25 °C. From these data, a method for the analysis of ternary liquid mixtures of these components has been developed. The limit of accuracy in the analysis of ternary mixtures of the pure components is 0.3%. The method can be applied to the analysis of commercial materials with an accuracy of 2.0%.


2004 ◽  
Vol 42 (1) ◽  
pp. 63-74 ◽  
Author(s):  
A. Touriño * ◽  
A. Gayol † ◽  
M. Hervello ‡ ◽  
V. Moreno ** ◽  
M. Iglesias §

2004 ◽  
Vol 69 (6) ◽  
pp. 461-475 ◽  
Author(s):  
A. Touriño ◽  
M. Hervello ◽  
V. Moreno ◽  
G. Marino ◽  
M. Iglesias

The refractive indices of ternary mixtures of chlorobenzene + n-hexane (n-heptane or n-octane) have been measured at 298.15 K and at atmospheric pressure over the whole composition diagram. Parameters of polynomial equations which represent the composition dependence of physical and derived properties are gathered. The experimental refractive indices and the ternary derived properties are compared with the data obtained using several predictive semi-empirical models. The use of the Soave?Redlich?Kwong (SRK) and the Peng?Robinson (PR) cubic equations of state with the Van der Waals one-fluid mixing rule, which incorporate different combining rules to predict refractive indices on mixing, are tested against the measured results, good agrement being obtained.


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