Temporal variations in helium and argon isotopic compositions of fumarolic gases at Kusatsu-Shirane volcano, Japan

Significant temporal variations in the chemical and isotopic composition of Taal fumarolic gas as well as in diffuse CO2 emission from Taal Main Crater Lake (TMLC) have been observed across the ~12 years of geochemical monitoring (Arpa et al., 2013; Hern&#225;ndez et a., 2017), with significant high CO2 degassing rates, typical of plume degassing volcanoes, measured in 2011 and 2017. In addition to these CO2 surveys at the TCML, soil CO2 efflux continuous monitoring was implemented at Taal volcano since 2016 and a clear increasing trend of the soil CO2 efflux in 2017 was also observed. Increasing trends on the fumarolic CO2/St, He/CO2, CO/CO2 and CO2/CH4 ratios were recorded during the period 2010-2011 whereas increasing SO2/H2S, H2/CO2 ratios were recorded during the period 2017-2018. A decreasing on the CO2/CH4 and CO2/St ratios was observed for 2017-2018. These changes are attributed to an increased contribution of magmatic fluids to the hydrothermal system in both periods. Observed changes in H2 and CO contents suggest increases in temperature and pressure in the upper parts of the hydrothermal system of Taal volcano. The 3He/4He ratios corrected (Rc/Ra), and &#948;13C of fumarolic gases also increased during the periods 2010-2011 and 2017-2018 before the eruption onset. During this study, diffuse CO2 emission values measured at TMCL showed a wide range of values from >0.5&#8201;g&#8201;m&#8722;2 d&#8722;1 up to 84,902 g&#8201;m&#8722;2 d&#8722;1. The observed relatively high and anomalous diffuse CO2 emission rate across the ~12 years reached values of 4,670 &#177; 159 t d-1 on March 24, 2011, and 3,858 &#177; 584 t d-1 on November 11, 2017. The average value of the soil CO2 efflux data measured by the geochemical station showed oscillations around background values until 14 March, 2017. Since then at 22:00 hours, a sharp increase of soil CO2 efflux from ~0.1 up to 1.1 kg m-2 d-1 was measured in 9 hours and continued to show a sustained increase in time up to 2.9 kg m-2 d-1 in 2 November, that represents the main long-term variation of the soil CO2 emission time series. All the above variations might be produced by two episodes of magmatic intrusion which favored degassing of a gas-rich magma at depth. During the 2010-2011 the magmatic intrusion of volatile-rich magma might have occurred from the mid-crustal storage region at shallower depths producing important changes in pressure and temperature conditions, whereas a new injection of more degassed magma into the deepest zone of the hydrothermal system occurring in 2017-2018 might have favored the accumulation of gases in the subsurface, promoting conditions leading to a phreatic eruption. These geochemical observations are most simply explained by magma recharge to the system, and represent the earliest warning precursor signals to the January 2020 eruptive activity.Arpa, M.C., et al., 2013. Bull. Volcanol. 75, 747. https://doi.org/10.1007/s00445-013-0747-9.Hern&#225;ndez, P.A., et al.,&#160; 2017. Geol. Soc. Lond. Spec. Publ. 437:131&#8211;152. https://doi.org/10.1144/SP437.17.

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Also tropical freshwater ostracods show a seasonal life cycle

10.5194/bg-2017-38 ◽

2017 ◽

Author(s):

Juliane Meyer ◽

Claudia Wrozyna ◽

Albrecht Leis ◽

Werner Piller

Keyword(s):

Life Cycle ◽

Environmental Factors ◽

Isotopic Composition ◽

Temporal Variations ◽

South Florida ◽

Population Variation ◽

Instrumental Data ◽

Mean Values ◽

Isotopic Signatures ◽

Isotopic Compositions

Abstract. Isotopic signatures of ostracod shells became common proxies for the reconstruction of paleo-environmental conditions. Their isotopic composition is the result of the composition of their host water and the phenology and ecology of the target species. The sum of spatial and temporal variations from environmental factors in the species habitat defines the maximum isotopic variation of a population during the time of their shell formation. Here we present isotopic signatures (δ18O, δ13C) of living Cytheridella ilosvayi (Ostracoda) and chemical and isotopic compositions of 14 simultaneously sampled freshwater habitats in South Florida and instrumental data of the region. The chemical and isotopic compositions of the selected sites characterize the different habitats and show the influence of the source water, biological activity and the duration of exposure to the surface. Isotopic signatures of C. ilosvayi shells correlate well with the isotopic composition of their host waters. Within-sample variability of repeated isotopic measurements of ostracod shells reflect habitat dependent ranges and indicate temperature and the δ18O composition of precipitation (δ18Oprec) as regional environmental factors responsible for the population variation. Instrumental data of water temperature and δ18Oprec were used to calculate the monthly variation of a theoretical calcite in rivers of Florida showing distinct seasonal variations in values and ranges. Different configurations of the theoretical calcite were compared to the within-sample variability to identify possible calcification periods of C. ilosvayi. For a plausible calcification period the ostracod isotopic range has to correlate with mean values of the theoretical calcite with a slight positive offset (vital effect) and the extension of the theoretical calcite range. The tested model suggests a seasonal calcification period of C. ilosvayi in early spring. The surprising seasonality of a tropical ostracod life cycle is probably coupled to the hydrologic cycle of Florida. The results of this study contribute to the application of ostracod isotopes in modern calibration studies and their potential use in paleontology.

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