scholarly journals Kinetics and Mechanism of Palladium (II) Catalyzed Oxidation of D-(+) Galactose by Cerium(IV) in Aqueous Acidic Medium

2014 ◽  
Vol 4 (3) ◽  
pp. 384-400 ◽  
Author(s):  
Manoj Ghosh
Keyword(s):  
Acidic Medium ◽  
Kinetics And Mechanism ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium

Kinetics and Mechanism of Ru(III)-Catalyzed Oxidation of Paracetamol by Chloramine-T in Aqueous Acidic Medium

2009 ◽  
Vol 132 (1-2) ◽  
pp. 285-291 ◽  
Author(s):  
Ajaya Kumar Singh ◽  
Reena Negi ◽  
Bhawana Jain ◽  
Yokraj Katre ◽  
Surya P. Singh ◽  
...  
Keyword(s):  
Acidic Medium ◽  
Kinetics And Mechanism ◽  
Chloramine T ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium

scholarly journals Kinetics and mechanism of cetyltrimethylammonium bromide catalyzed oxidation of diethylene glycol by chloramine-T in acidic medium

2003 ◽  
Vol 68 (7) ◽  
pp. 535-542 ◽  
Author(s):  
V.W. Bhagwat ◽  
J. Tiwari ◽  
A. Choube ◽  
B. Pare
Keyword(s):  
Diethylene Glycol ◽  
Acidic Medium ◽  
Cetyltrimethylammonium Bromide ◽  
Reaction Rate ◽  
Chloride Ions ◽  
Kinetics And Mechanism ◽  
Product Analysis ◽  
Rate Determining Step ◽  
Chloramine T ◽  
Catalyzed Oxidation

The kinetics and mechanism of the C16TABcatalyzed oxidation of diethylene glycol (2,2?-oxydiethanol) by chloramine-T in acidic medium has been studied. The reaction has a first-order dependence on chloramine-T. With excess concentrations of other reactants, the reaction rate follows fractional order kinetics with respect to [diethylene glycol]. The micellar effect due to cetyltrimethylammonium bromide, a cationic surfactant, has been studied. The reaction is catalyzed by chloride ions as well. The small salt effect and increase in the reaction rate with increasing dielectric constant suggest the involvement of neutral molecules in the rate determining step. Addition of p-toluenesulfonamide retards the reaction rate. On the basis of product analysis, a pertinent mechanism is proposed.

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