No thermodynamic description was performed for the Co-Mg binary system
according to literature review. Consequently, this binary system has been
investigated by means of CALPHAD (CALculation of PHAse Diagrams) approach in
the present work. The experimental phase diagram and thermodynamic data
available in the literature were critically assessed. Based on the reliable
literature data, a new set of self-consistent thermodynamic parameters for
the Co-Mg system is obtained. The calculated results agree well with the
experimental data from the literature, indicating the reasonability of the
present thermodynamic optimization.