Conversion of a double‐tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process

We present the first example of a silver double‐tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform...

A tetranuclear nickel cluster isolated in multiple high-valent states

An all Ni(iii) tetranuclear cluster is isolated. Metal-centered oxidations are proposed for it and its mixed-valent congeners, supported by crystallographic, spectroscopic, and computational methods.

Synthesis, Crystal Structures and Magnetic Properties of Mixed-Valent Tetranuclear Complexes with Y-Shaped MnII2MnIII2 Core

Tetranuclear MnII2MnIII2 complexes with 1,3-bis(5-bromo-3-metoxysalicylidenaminomethyl)-2-propanol (H3bmsap) and 1,3-bis(5-chloro-3-methoxysalicylidenaminomethyl)-2-propanol (H3cmsap), [Mn4(bmsap)2(CH3CO2)3(CH3O)] (3) and [Mn4(cmsap)2(CH3CO2)3(CH3O)] (4), were synthesized and characterized by elemental analysis, infrared and diffused reflectance spectra and variable-temperature magnetic susceptibility measurements in the 2–300 K range. The crystal structures of 3 and 4 revealed a Y-shaped tetranuclear manganese cluster formed by the two Schiff-base ligands, three kinds of acetato ligands (bidentate, syn–anti-bridging, and syn–syn-bridging), and µ-methoxido ligand. The magnetic data showed the magnetic interactions among the four manganese atoms are antiferromagnetic as a whole within the tetranuclear cluster.

Electrocatalytic water oxidation studies of a tetranuclear Cu(ii) complex with cubane-like core Cu4(μ3-O)4

A bio-inspired cubane-like tetranuclear cluster [Cu4(pdmH)4(OAc)2](NO3)2·3H2O can electrocatalyze water oxidation under aqueous alkaline conditions through a PCET process.

Syntheses, crystal structures, magnetochemistry and catechol oxidase activity of a tetracopper(ii) compound and a new type of dicopper(ii)-based 1D coordination polymer

One phenoxo–hydroxo bridged tetranuclear cluster and one phenoxo-µ1,1-azido-µ1,3-azido bridged one-dimensional coordination polymer of copper(ii) derived from a Schiff base ligand are described.