Detection and Inhibition of Refractory Steel Corrosion by Rhodamine-Based Compound

A rhodamine-based fluorescent compound, spiro[1H-isoindole-1,9′-[9H]xanthen] -3(2H)-one, ′,6′-bis(diethylamino)-2-[(1-methylethylidene)-amino] (RB1), is developed to detect and inhibit the refractory steel corrosion in 3% NaCl solution. The inhibition effect was evaluated by electrochemical measurements. RB1 suppresses the cathodic corrosion reaction and shifts the corrosion potential toward more negative values. RB1 exhibits a turn-on fluorescence emission in the presence of Fe 3+ ions. The selectivity of RB1 over other commonly coexistent Cu2+, Fe 2+ and Mn2+ was investigated. The variation of the fluorescence intensity is correlated to that of weight-loss. RB1 has a potential application as corrosion inhibitor and corrosion indicator in some industry process.

Effect of Process Parameters on the Temperature of 4Cr9Si2 Martensite Refractory Steel during CWR

Based on the constitutive relationship of 4Cr9Si2 martensite refractory steel obtained by Gleeble-1500 hot simulation isothermal compression, a finite element model of Cross Wedge Rolling was build up for 4Cr9Si2 Martensite and the heat conduction, convection, plastic work and friction work were taken in account in the model. The forming process of 4Cr9Si2 martensite refractory steel by cross wedge rolling was simulated by means of DEFORM-3D software. The influence regularities of temperature of rolling process parameters were obtained: temperature rise rapidly result from plastic work and friction work in the cross-section at the process of rolling, with the completion of rolled piece cross-section, temperature descending due to heat conduction and radiation with atmosphere. The rolled piece temperature difference decrease with rolling speed and die preheat temperature increasing, the billet heating temperature is little for rolled piece temperature difference compared with rolling speed and die preheat temperature.