Спектральные моменты характеристик бинарных взаимодействий между линейными молекулами

A new approach to derive symmetrized expressions of leading classical moments of spectral distributions characterizing different anisotropic terms of the interaction potential for the case of two liear molecules is presented. The results allow to calculate diffuse shapes formed by transitions between continuous eigenstates of a molecular pair and open the way to account for the nonMarkov effects (due to finite collision durations) in the rotatonal relaxation matrix of an arbitrary rank. The approach is also applied to the spectral moments of vector and tensor characteristics determining the band intensities in the collision-induced spectra of linear molecules. Generally, the use of symmetrized expressions lead to considerably faster computer codes.