rhodium carbenoid
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scholarly journals Urea Insertion Reaction of Rhodium-Carbenoid

2018 ◽  
Vol 66 (11) ◽  
pp. 1041-1047 ◽  
Author(s):  
Yoshinori Hashimoto ◽  
Masato Kono ◽  
Shingo Harada ◽  
Tetsuhiro Nemoto
Keyword(s):  
Insertion Reaction ◽  
Rhodium Carbenoid

A computational mechanistic study of substrate-controlled competitive O–H and C–H insertion reactions catalyzed by dirhodium(ii) carbenoids: insight into the origin of chemoselectivity

2018 ◽  
Vol 5 (15) ◽  
pp. 2353-2363 ◽  
Author(s):  
Li-Han Zhu ◽  
Hai-Yan Yuan ◽  
Wen-Liang Li ◽  
Jing-Ping Zhang
Keyword(s):  
Dft Calculations ◽  
Mechanistic Study ◽  
Insertion Reactions ◽  
Rhodium Carbenoid ◽  
Insight Into

DFT calculations disclosed the chemoselectivity of rhodium carbenoid and water co-catalyzed O–H and C–H insertion reactions with three 1,3-diketone substrates.

A novel approach to 5H-pyrazino[2,3-b]indolesviaannulation of 3-diazoindolin-2-imines with 2H-azirines or 5-alkoxyisoxazoles under Rh(ii) catalysis

2018 ◽  
Vol 16 (1) ◽  
pp. 38-42 ◽  
Author(s):  
Julia O. Ruvinskaya ◽  
Nikolai V. Rostovskii ◽  
Ilya P. Filippov ◽  
Alexander F. Khlebnikov ◽  
Mikhail S. Novikov
Keyword(s):  
Diazo Compounds ◽  
Novel Approach ◽  
Rhodium Carbenoid

The first example of rhodium carbenoid-mediated intermolecular annulation of cyclic diazo compounds with azirines and alkoxyisoxazoles is presented.

Rhodium Carbenoid Initiated O–H Insertion/Aldol/Oxy-Cope Cascade for the Stereoselective Synthesis of Functionalized Oxacycles

2016 ◽  
Vol 18 (24) ◽  
pp. 6340-6343 ◽  
Author(s):  
Kiran Chinthapally ◽  
Nicholas P. Massaro ◽  
Indrajeet Sharma
Keyword(s):  
Stereoselective Synthesis ◽  
Rhodium Carbenoid

ChemInform Abstract: 4-Halo-2-azabuta-1,3-dienes as Intermediates in the Rhodium Carbenoid-Initiated Transformation of 2-Halo-2H-azirines into 2,3-Dihydroazetes and 2,5-Dihydrooxazoles.

ChemInform ◽  
2015 ◽  
Vol 46 (42) ◽  
pp. no-no
Author(s):  
Ilia A. Smetanin ◽  
Mikhail S. Novikov ◽  
Nikolai V. Rostovskii ◽  
Alexander F. Khlebnikov ◽  
Galina L. Starova ◽  
...  
Keyword(s):  
Rhodium Carbenoid

4-Halo-2-azabuta-1,3-dienes as intermediates in the rhodium carbenoid-initiated transformation of 2-halo-2H-azirines into 2,3-dihydroazetes and 2,5-dihydrooxazoles

Tetrahedron ◽  
2015 ◽  
Vol 71 (28) ◽  
pp. 4616-4628 ◽  
Author(s):  
Ilia A. Smetanin ◽  
Mikhail S. Novikov ◽  
Nikolai V. Rostovskii ◽  
Alexander F. Khlebnikov ◽  
Galina L. Starova ◽  
...  
Keyword(s):  
Rhodium Carbenoid

scholarly journals Late-stage C–H functionalization of complex alkaloids and drug molecules via intermolecular rhodium-carbenoid insertion

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Jing He ◽  
Lawrence G. Hamann ◽  
Huw M. L. Davies ◽  
Rohan E. J. Beckwith
Keyword(s):  
Late Stage ◽  
Drug Molecules ◽  
Rhodium Carbenoid
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