Synthesis and Characterization of Novel Bio-Chiral Dopants Obtained from Bio-Betulin Produced by a Fermentation Process

Cholesteric liquid crystals are frequently produced by the addition of chiral dopants to achiral nematic hosts. We report here the synthesis and performance of chiral dopants obtained from bio-betulin produced by a fermentation process. An important aspect of this work is to point out that the fermentation process used to obtain the starting materials is much easier and cheaper when carried out in large volumes than isolating it from the natural product. The performance of the dopants obtained from bio-betulin is indistinguishable from those obtained from commercially available synthetic betulin.

Mechanisms of Chiral Transfer in Optically Active Dopant – Nematic Liquid Crystal Systems

Induction of helical mesophases by incorporating chiral dopants into the nematics matrix is the promising modern trends in the chemistry of liquid crystals. This process is associated with a unique phenomenon - an amplification of chirality in liquid-crystalline phases, which ensures the detection of enantiomers by their chiral induction, much more sensitive than other methods. The relevance of this approach is due to the need to create perspective electro-optical devices operating with ultra-low control voltages based on twist effects, chromatographic stationary phases with high chiral selectivity, flexible magnets, photo-sensitive nanostructures, and other smart LC materials. The successful solution of these problems is impossible without experimental research and theoretical comprehension of the mechanisms of third level chiral transfer optically active dopant – nematic liquid crystal. In the last decade, a large number of works have appeared on the solution of these problems. This review is devoted to a generalization of the experimental results and a theoretical description of the transfer of molecular chirality to orientationally ordered systems with the participation of both chiral molecular substituents with an asymmetric carbon atom and planar or quasi-planar fragments chirally distorted relative to each other. The stereochemical aspects of induction associated with the structural correspondences of the dopant and nematic liquid crystal, as well as the main classes of optically active additives, are discussed. Application of metal complexes, both Werner and macroheterocyclic, are presented. Special attention is paid to the results of the mechanisms study of chiral transfer due to various intermolecular interactions: hydrogen bonding, axial coordination, and the formation of inclusion compounds. The high efficiency of induction of spiral mesophases has been demonstrated with a combination of different self-assembly mechanisms in liquid crystal - chiral additive systems.

Broadband Multichannel Optical Vortex Generators via Patterned Double-Layer Reverse-Twist Liquid Crystal Polymer

The capacity of an optical communication system can be greatly increased by using separate orbital angular momentum (OAM) modes as independent channels for signal transmission and encryption. At present, a transmissive OAM mode generator compatible with wavelength division multiplexing is being highly pursued. Here, we introduce a specific double-layer reverse-twist configuration into liquid crystal polymer (LCP) to overcome wavelength dependency. With this design, broadband-applicable OAM array generators are proposed and demonstrated. A Damman vortex grating and a Damman q-plate were encoded via photopatterning two subsequent LCP layers adopted with oppositely handed chiral dopants. Rectangular and hexagonal OAM arrays with mode conversion efficiencies exceeding 40.1% and 51.0% in the ranges of 530 to 930 nm, respectively, are presented. This provides a simple and broadband efficient strategy for beam shaping.