Characterization of hydrothermal events associated with the occurrence of copper-molybdenum minerals in the El Chucho creek at Cerrito, Valle del Cauca-Colombia

At El Chucho creek, located to the west of the Valle del Cauca department in Colombia, some hydrothermal alterations affecting the Buga Batholith rocks and dykes of porphyritic quartz-dioritic and tonalitic composition were identified. These lithological units host mineral occurrences of pyrite, chalcopyrite, and molybdenite that occur disseminated in the rocks or associated with quartz veinlets. The hydrothermal alterations identified were phyllic, propylitic, and, in minor quantity, potassic. The two firsts alterations’ distribution is related to structures and pervasive, whereas the last one seems restricted to contact zones of porphyritic dykes on tonalite. Microthermometric data were acquired i) on quartz veinlets of 1 cm thick over a phyllic alteration zone, and ii) on quartz veinlet of 1 cm thick with chalcopyrite ± molybdenite and copper silicates, both veinlets cutting the phaneritic tonalite. Those data suggest that the mineralizing fluids have an aqueous-saline chemical system and were trapped under low volatile content. The microthermal data allowed authors to identify two mineralizing events. One of them of higher temperature, with homogenization temperatures between 275°C-480°C; as the second event is characterized by lower homogenization temperatures that range from 100°C to 139°C.

Porphyry-related high-sulfidation mineralization early in Central American Arc development: Cerro Quema deposit, Azuero Peninsula, Panama

The 70.74 to 70.66 Ma age range for three molybdenite samples accompanying pyrite- and enargite-bearing assemblages effectively constrains an earliest Maastrichtian age for the high-sulfidation Au-Cu mineralization at Cerro Quema, Panama. The epithermal system was contemporaneous with emplacement of a composite dacite dome complex in a geotectonic setting transitional from mafic, primitive intraoceanic (Azuero Protoarc) to more evolved island arc magmatism (Azuero Arc), during initial construction of the Central American land bridge at the trailing edge of the Caribbean Large Igneous Province (CLIP). The molybdenite ages confirm the rapid evolution of the earliest stages of the Central American Arc, from subduction initiation at 75–73 Ma to arc maturation at 71 Ma. A porphyry connection is apparent at Cerro Quema and characterized by highly contorted, banded, and planar quartz-veinlet stockworks and sheeted zones in pyrophyllite- and sericite-bearing patchy-textured rock. These are cut by ledges of quartz, alunite, and dickite, which implies overprinting of the advanced argillic lithocap onto the underlying porphyry environment. Hydrothermal telescoping resulted from synmineralization uplift congruent with an actively emerging volcanic arc, which the Re-Os molybdenite dates accurately constrain at 71 Ma, presumably as a far-field effect of collision between the leading edge of the CLIP with parts of North and South America.