Orientational arrest in dense suspensions of elliptical particles under oscillatory shear flows

We study the rheological response of dense suspensions of elliptical particles, with an aspect ratio equal to 3, under oscillatory shear flows and imposed pressure by numerical simulations. Like for the isotropic particles, we find that the oscillatory shear flows respect the Cox-Merz rule at large oscillatory strains but differ at low strains, with a lower viscosity than the steady shear and higher shear jamming packing fractions. However, unlike the isotropic cases (i.e., discs and spheres), frictionless ellipses get dynamically arrested in their initial orientational configuration at small oscillatory strains. We illustrate this by starting at two different configurations with different nematic order parameters and the average orientation of the particles. Surprisingly, the overall orientation in the frictionless case is uncoupled to the rheological response close to jamming, and the rheology is only controlled by the average number of contacts and the oscillatory strain. Having larger oscillatory strains or adding friction does, however, help the system escape these orientational arrested states, which are evolving to a disordered state independent of the initial configuration at low strains and ordered ones at large strains.

A jamming plane of sphere packings

The concept of jamming has attracted great research interest due to its broad relevance in soft-matter, such as liquids, glasses, colloids, foams, and granular materials, and its deep connection to sphere packing and optimization problems. Here, we show that the domain of amorphous jammed states of frictionless spheres can be significantly extended, from the well-known jamming-point at a fixed density, to a jamming-plane that spans the density and shear strain axes. We explore the jamming-plane, via athermal and thermal simulations of compression and shear jamming, with initial equilibrium configurations prepared by an efficient swap algorithm. The jamming-plane can be divided into reversible-jamming and irreversible-jamming regimes, based on the reversibility of the route from the initial configuration to jamming. Our results suggest that the irreversible-jamming behavior reflects an escape from the metastable glass basin to which the initial configuration belongs to or the absence of such basins. All jammed states, either compression- or shear-jammed, are isostatic and exhibit jamming criticality of the same universality class. However, the anisotropy of contact networks nontrivially depends on the jamming density and strain. Among all state points on the jamming-plane, the jamming-point is a unique one with the minimum jamming density and the maximum randomness. For crystalline packings, the jamming-plane shrinks into a single shear jamming-line that is independent of initial configurations. Our study paves the way for solving the long-standing random close-packing problem and provides a more complete framework to understand jamming.

The role of solvent molecular weight in shear thickening and shear jamming

We find that tuning solvent molecular weight can mediate frictional interactions between suspended particles, drastically impacting the suspension rheology.

Dilatancy, shear jamming, and a generalized jamming phase diagram of frictionless sphere packings

Frictionless packings exhibit dilatancy and shear jamming, contrary to previous expectations, depending crucially on the existence of a “jamming line” above the minimal jamming density (J-Point), and with strikingly different rheological behaviour.