Crystal Engineering of Coordination Polymers via Solvothermal In Situ Metal-Ligand Reactions

2009 ◽  
pp. 63-86 ◽  
Author(s):  
Jie-Peng Zhang ◽  
Xiao-Ming Chen
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Metal Ligand

Crystal engineering of cadmium coordination polymers decorated with nitro-functionalized thiophene-2,5-dicarboxylate and structurally related bis(imidazole) ligands with varying flexibility

CrystEngComm ◽  
2015 ◽  
Vol 17 (33) ◽  
pp. 6441-6449 ◽  
Author(s):  
Li-Ping Xue ◽  
Zhao-Hao Li ◽  
Lu-Fang Ma ◽  
Li-Ya Wang
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Crystal Engineering ◽  
Imidazole Ligand ◽  
Dicarboxylate Ligand ◽  
Ligand Synthesis ◽  
Imidazole Ligands

Five bis(imidazole) ligand modulated cadmium coordination polymers based on a new nitro-functionalized thiophene-2,5-dicarboxylate ligand or 4-nitro-thiophene-2-carboxylic acid involving in situ ligand synthesis.

Four unexpected lanthanide coordination polymers involving in situ reaction of solvent N, N-Dimethylformamide

2015 ◽  
Vol 225 ◽  
pp. 216-221 ◽  
Author(s):  
Jun-Cheng Jin ◽  
Wen-Quan Tong ◽  
Ai-Yun Fu ◽  
Cheng-Gen Xie ◽  
Wen-Gui Chang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
In Situ Reaction ◽  
Lanthanide Coordination Polymers

The construction of Cu(i)/Cu(ii) coordination polymers based on pyrazine–carboxylate: Structural diversity tuned by in situ hydrolysis reaction

CrystEngComm ◽  
2013 ◽  
Vol 15 (26) ◽  
pp. 5359 ◽  
Author(s):  
Zhen-Zhen Wen ◽  
Xi-Ling Wen ◽  
Song-Liang Cai ◽  
Sheng-Run Zheng ◽  
Jun Fan ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity ◽  
Hydrolysis Reaction

Gold−Gold Interactions as Crystal Engineering Design Elements in Heterobimetallic Coordination Polymers

2001 ◽  
Vol 40 (23) ◽  
pp. 6026-6034 ◽  
Author(s):  
Daniel B. Leznoff ◽  
Bao-Yu Xue ◽  
Raymond J. Batchelor ◽  
Frederick W. B. Einstein ◽  
Brian O. Patrick
Keyword(s):  
Engineering Design ◽  
Coordination Polymers ◽  
Crystal Engineering ◽  
Design Elements

A threefold interpenetrated two-dimensional zinc(II) supramolecular architecture based on 3-nitrobenzoic acid and 4,4′-bipyridine

2016 ◽  
Vol 72 (2) ◽  
pp. 128-132 ◽  
Author(s):  
Long Tang ◽  
Ji-Jiang Wang ◽  
Feng Fu ◽  
Sheng-Wen Wang ◽  
Qi-Rui Liu
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Critical Factor ◽  
Building Blocks ◽  
Zigzag Chain ◽  
Great Success ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Hydrothermal Conditions ◽  
Nitrobenzoic Acid

With regard to crystal engineering, building block or modular assembly methodologies have shown great success in the design and construction of metal–organic coordination polymers. The critical factor for the construction of coordination polymers is the rational choice of the organic building blocks and the metal centre. The reaction of Zn(OAc)2·2H2O (OAc is acetate) with 3-nitrobenzoic acid (HNBA) and 4,4′-bipyridine (4,4′-bipy) under hydrothermal conditions produced a two-dimensional zinc(II) supramolecular architecture,catena-poly[[bis(3-nitrobenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′], [Zn(C7H4NO4)2(C10H8N2)]nor [Zn(NBA)2(4,4′-bipy)]n, which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction analysis. The ZnIIions are connected by the 4,4′-bipy ligands to form a one-dimensional zigzag chain and the chains are decorated with anionic NBA ligands which interact further through aromatic π–π stacking interactions, expanding the structure into a threefold interpenetrated two-dimensional supramolecular architecture. The solid-state fluorescence analysis indicates a slight blue shift compared with pure 4,4′-bipyridine and HNBA.

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