Acid-Base Accounting Associated with Acid Rock Drainage

Author(s):  
Bruce W. Downing
2003 ◽  
Vol 56 (3) ◽  
pp. 201-206 ◽  
Author(s):  
Luciana Xavier de Lemos Capanema ◽  
Virgínia Sampaio Teixeira Ciminelli

This work is aimed at evaluating the potential of Acid Rock Drainage (ARD) from two Brazilian gold sulfidic ore samples, by means of using three of the most traditional ARD prediction techniques: Standard Acid Base Accounting and Modified Acid Base Accounting, as static methods, and humidity cells, as a kinetic method. Samples were submitted to chemical and mineralogical characterization that indicated the presence of traces of sulfide minerals, such as pyrite, arsenopyrite, pyrrhotite and of carbonates, calcite and dolomite. While the Standard ABA results were inconclusive, the Modified ABA NNP results and NP/AP ratio suggested a tendency of TP01 and WP01 being acid generators, this tendency being slightly stronger for sample WP01. So, a kinetic test was conducted to elucidate the results. The humidity cells results for samples TP01 and WP01 indicated the probable sulfide oxidation to produce acid, subsequently neutralized by alkalinity generated by the carbonates. Based on the results, one can conclude that although sample WP01 has a slightly higher ARD generation potential than TP01, these samples can be at different stages of ARD process, or better, TP01 is at a more advanced stage of ARD production than WP01. The determinant role of the kinetic tests is highlighted by the results.


2017 ◽  
Vol 16 (9) ◽  
pp. 2089-2096
Author(s):  
Artwell Kanda ◽  
George Nyamadzawo ◽  
Jephita Gotosa ◽  
Nathan Nyamutora ◽  
Willis Gwenzi

2021 ◽  
pp. geochem2021-066
Author(s):  
S.J. Day

Blending of potentially acid generating (PAG) waste rock with non-PAG waste rock to create a rock mixture which performs as non-PAG is a possible approach to permanent prevention of acid rock drainage (ARD) for PAG waste rock. In 2012, a field weathering study using 300 kg samples was implemented at Teck Coal's Quintette Project located in northeastern British Columbia, Canada to test the prevention of acid generation in the PAG waste rock by dissolved carbonate leached from overlying non-PAG waste rock and direct neutralization of acidic water from PAG waste rock by contact with non-PAG waste rock.After eight years of monitoring the experiments, the layered non-PAG on PAG barrels provided proof-of-concept that as the thickness of the PAG layer increases relative to the thickness of the non-PAG layers, acidic waters are more likely to be produced. The PAG on non-PAG layering has resulted in non-acidic water and no indications of metal leaching despite accelerated oxidation in the PAG layer shown by sulphate loadings. The study has demonstrated that the scale of heterogeneity of PAG and non-PAG materials is a critical consideration for providing certainty that rock blends designed to be non-PAG will perform as non-PAG in perpetuity. This is contrary to the standard paradigm in which an excess of acid-consuming minerals is often considered sufficient alone to ensure ARD is not produced.


2017 ◽  
Vol 51 (19) ◽  
pp. 11317-11325 ◽  
Author(s):  
Rong Fan ◽  
Michael D. Short ◽  
Sheng-Jia Zeng ◽  
Gujie Qian ◽  
Jun Li ◽  
...  
Keyword(s):  

Author(s):  
Rudy Sayoga Gautama ◽  
Ginting Jalu Kusuma ◽  
Dyah Firgiani ◽  
Salmawati Mustakar ◽  
Prasetyaningtyas Ekarini

Sign in / Sign up

Export Citation Format

Share Document