Degradation mechanism and life prediction of tailings and waste rock aggregate geopolymer concrete under freeze-thaw corrosion

To study the durability of tailings and waste rock aggregate geopolymer concrete (TWGPC), a large number of tailings and waste rock were used to replace natural sand and stone as aggregates, and a fly ash geopolymer was used to replace cement as cementing material to prepare TWGPC. The slow freezing method was used to carry out single freeze-thaw and freeze-thaw corrosion tests. Scanning electron microscopy and energy dispersive spectroscopy (SEM–EDS) were used to analyse the microstructure and reaction products of TWGPC. The degradation mechanism of TWGPC was studied, and the life of TWGPC was predicted. The results show that the higher the concentration of corrosion solution was, the more significant the change trend of the mechanical properties test results. In the early stage of the cycle, acinar gypsum and short columnar ettringite were generated to fill the pores and improve the compactness and frost resistance of TWGPC. In the late stage of the cycle: calcium-silicate-hydrate (C-S-H) was decomposed and gradually replaced by magnesium-silicate-hydrate (M-S-H). The cohesion between mortar and aggregate was reduced, and a large number of products were generated. Cl- inhibited the transmission rate of SO42- and reduced the erosion effect of SO42- on TWGPC. The single freezing-thawing life prediction model had high accuracy, and the life prediction conclusion based on reliability was consistent with the appearance damage analysis, mechanical property testing and microscopic morphology analysis.

Assessment of the woody plant species vital condition distributed on the devastated lands of the iron ore dump

The actuality of the research is caused by the importance of understanding the laws of natural distribution of woody and shrub plant species on devastated lands of iron ore dumps of Kryviy Rih as a theoretical prerequisite for harmonizing the ecological environment of industrial regions. The aim of the research is to assess the current vital condition of woody and shrub plant species that naturally grow on devastated lands of the iron ore dump from the standpoint of the ecosystem approach. The materials of the work were the results of our own research, which were carried out according to generally accepted methods during 2020–2021 on the territory of Petrovsky waste rock dump of Kryviy Rih iron ore basin. The assessment of the current vital condition was carried out according to the method of V. A. Alekseyev. Presently, the vegetation on Petrovsky waste rock dump, which is a model for the region, is represented by natural groups, has a fragmented character and is a sparse forest. It has been established that 32 species of woody and shrub plant species (25 genera and 15 families) naturally grow within Petrovsky waste rock dump. The current vital condition of woody and shrub plant species in the dump was assessed as «weakened» (65–71 conventional points by V. A. Alekseyev’s scale). Such numerical values of the vitality of the forest stand are 21–28% lower than the control indicators (natural groupings of Gurivka forest). Our results indicate that the ecological conditions of the devastated lands of Petrovsky waste rock dump are relatively favourable for the growth and development of woody and shrub plant species. It was found that European birch (Betula pendula Roth.), ash-leaved maple (Acer negundo L.) and acacia (Robinia pseudoacacia L.) are quite adapted to the habitat conditions of the dump. The vital condition of these species was assessed as «healthy»: 90–95 conventional points by V. A. Alekseyev’s scale.

Grain size distribution of waste rock masses of Kuzbass coal strip mines

Grain size distribution as a structural characteristic of waste rock and bulk masses in the course of mining and construction works acquires quantitative values in the process of rock blasting and hauling of rock mass. Such physical-mechanical and structural-textural parameters of a rock mass, as the ultimate strength of rocks and rock mass, fracturing, diameter of the natural rock jointing, have a significant impact on the blasted rock mass grain size distribution. On the other hand, such characteristics as stability, permeability of waste rock masses largely depend on the lithology and grain size distribution of the loosened rocks composing waste rock dumps and their height distribution within a dump. The paper describes the findings of the study of the grain size distribution of waste rock masses of Kuzbass coal strip mines and the features of its spatial variations within the masses. The textures of the bulk masses and physical and technical properties of the stacked rocks were studied both at the Kuzbass waste rock sites and in laboratory conditions. The grain size distribution of the fine lump part of the dumps with the lump size up to 50 mm was investigated by sieve method according to GOST 12536–2014, and the medium and large lump part was studied using oblique photoplanimetry. The field observations showed that the bottom part of the rock dumps, dumped by peripheral bulldozer or excavator methods was composed of coarse fraction with average lump size of: d_cr = 0.8–1 m, while the middle part, of rock lumps of d_cr = 0.4–0.6 m, and the upper part, mainly of fine fraction with lump size of less than 0.1 m. The ratio of length, width, and thickness of the blasted rock lumps was 1:0.85:0.8, which corresponds to elongated-flattened shape of the lumps. This requires significant number of coordinates for describing the lump positions in the rock mass, as well as taking into account the moments of inertia when modeling the motion of such lumps until they reach a stable position. Up-to-date non-commercial or commercial software and corresponding hardware can be used to take into account non-isometric shape of the lumps when modeling their motion.

Hydraulic Conductivity Testing and Destructive Sampling of Field-Scale Mine Waste Test Piles

A commingled waste rock and tailings test pile and a waste rock test pile were evaluated to determine saturated hydraulic conductivity and destructively sampled to measure dry density. The commingled test pile contained a mixture of filtered tailings and waste rock blended to isolate waste rock particles as inclusions within the tailings matrix. Test piles were constructed in the shape of truncated 5-m tall pyramids with 25-m base sides and flat 5-m × 5-m top surfaces, and instrumented to monitor water content (and additional geochemical indicator parameters) within the test pile and seepage from the base of the pile. Piles were decommissioned after 26 months of operation. Saturated hydraulic conductivities were measured using sealed double ring infiltrometers (2.4-m square outer-ring and 1-m square inner-ring). Tensiometers and embedded water content sensors were used to measure progression of the wetting front, and the final location of the wetting front in the commingled test pile was directly measured during decommissioning. Field-measured saturated hydraulic conductivities were compared to laboratory-measured results intended to simulate the test piles. Despite having a lower average density, the commingled waste rock and tailings had a hydraulic conductivity approximately 2.5-times lower than the waste rock.

Potential of Mechanochemically Activated Sulfidic Mining Waste Rock for Alkali Activation

Sulfidic mining waste rock is a side stream from the mining industry with a potential environmental burden. Alkali activation is a promising method for transforming mining waste into construction materials. However, the low reactivity of minerals can be a sizeable challenge in alkali activation. In the present study, the reactivity of waste rock was enhanced by mechanochemical treatment with a LiCl-containing grinding aid. X-ray diffraction (XRD) and diffuse reflectance infrared Fourier transform (DRIFT) analysis were utilized to display the structural alteration of individual minerals. A schematic implication of the grinding mechanism of mica was provided according to the results of transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The alkaline solubility displayed the enhanced chemical reactivity of the waste rock, in which Si and Al solubility increased by roughly 10 times and 40 times, respectively. The amorphization of aluminosilicate is achieved through chemical assisted mechanochemical activation. Sulfidic waste rock, as the sole precursor in alkali activation, achieved a 28-day compressive strength exceeding 10 MPa under ambient curing conditions. The simulation of the upscaled grinding process was conducted via the HSC Chemistry® software with a life-cycle assessment. The results showed that mining waste rock can be a promising candidate for geopolymer production with a lower carbon footprint, compared to traditional Portland cement. Graphical Abstract

Small-scale field evaluation of geochemical blending of waste rock to mitigate acid rock drainage potential

Blending of potentially acid generating (PAG) waste rock with non-PAG waste rock to create a rock mixture which performs as non-PAG is a possible approach to permanent prevention of acid rock drainage (ARD) for PAG waste rock. In 2012, a field weathering study using 300 kg samples was implemented at Teck Coal's Quintette Project located in northeastern British Columbia, Canada to test the prevention of acid generation in the PAG waste rock by dissolved carbonate leached from overlying non-PAG waste rock and direct neutralization of acidic water from PAG waste rock by contact with non-PAG waste rock.After eight years of monitoring the experiments, the layered non-PAG on PAG barrels provided proof-of-concept that as the thickness of the PAG layer increases relative to the thickness of the non-PAG layers, acidic waters are more likely to be produced. The PAG on non-PAG layering has resulted in non-acidic water and no indications of metal leaching despite accelerated oxidation in the PAG layer shown by sulphate loadings. The study has demonstrated that the scale of heterogeneity of PAG and non-PAG materials is a critical consideration for providing certainty that rock blends designed to be non-PAG will perform as non-PAG in perpetuity. This is contrary to the standard paradigm in which an excess of acid-consuming minerals is often considered sufficient alone to ensure ARD is not produced.

Optimization of Conditions for Processing of Lead–Zinc Ores Enrichment Tailings of East Kazakhstan

This article presents the results of studies of a low-waste technology for processing enrichment tailings using a combined enrichment–hydrometallurgical method. After washing the enrichment tailings from harmful products and reducing their size, multi-stage flotation of the crushed material of the enrichment tailings was carried out. The use of a new reagent in the flotation process was studied in order to ensure the maximum recovery of the main valuable components from the enrichment tailings. A new collector of Aero 7249 (Shenyang Florrea Chemicals Co., Ltd., Shenyang, China) type was used for the flotation. The recovery of valuable components was as follows: Cu, 6.78%; Zn, 91.69%; Pb, 80.81%; Au, 95.90%; Ag, 82.50%; Fe, 78.78%. Tailings of the flotation were re-enriched using a fatty acid collector (sodium oleate). Additional (reverse) flotation resulted in obtaining a product corresponding to the composition of building sand in terms of the content of valuable components of the waste rock. The studies of the conditions for processing the enrichment tailings of lead–zinc ore indicate the possibility of its optimization in order to maximize the involvement of waste in the production.

Development and Validation of a Dynamic Model for Flotation Predictive Control Incorporating Froth Physics

In mining, froth flotation is the largest tonnage separation process used to separate valuable minerals from waste rock [...]