Catalytic Carbon-Sulfur Bond Activation and Transformations

2014 ◽  
pp. 317-345 ◽  
Author(s):  
Zhengkun Yu
Keyword(s):  
Bond Activation ◽  
Sulfur Bond

Novel Intramolecular CAryl–S Bond Activation by an Electron Rich, Ring-Expanded-NHC-Rh centre: A Combined Experimental and DFT Study

2011 ◽  
Vol 64 (8) ◽  
pp. 1141 ◽  
Author(s):  
Abeer Binobaid ◽  
Kingsley J. Cavell ◽  
Mikhail S. Nechaev ◽  
Benson M. Kariuki
Keyword(s):  
Bond Activation ◽  
Reaction Pathway ◽  
Heterocyclic Carbenes ◽  
Dft Study ◽  
Dft Studies ◽  
X Ray ◽  
Carbene Complex ◽  
Donor Capacity ◽  
Insight Into ◽  
Sulfur Bond

The reaction of (o-MeSPh)-N-functionalized tetrahydropyrimidinium salts with KN(SiMe3)2 and [Rh(COD)Cl]2 in THF leads to the formation of a novel dimeric RhIII bis-carbene complex. The reaction involves the unexpected cleavage/oxidative addition of the aryl-sulfur bond to give dimeric metallated RhIII with bridging MeS< moieties. This unusual reaction is probably a consequence of the sterically imposing structure and strong donor capacity of ring-expanded N-heterocyclic carbenes (RE-NHCs). An X-ray structure of the [(Ph,DIPP-NHC)Rh(Cl)(SMe)2] product complex has been obtained, and DFT studies were undertaken to gain an insight into the reaction pathway.

Theory of Carbon-Sulfur Bond Activation by Small Metal Sulfide Particles

1994 ◽  
Vol 116 (10) ◽  
pp. 4427-4439 ◽  
Author(s):  
Matthew Neurock ◽  
Rutger A. van Santen
Keyword(s):  
Bond Activation ◽  
Metal Sulfide ◽  
Sulfur Bond

Converting Thioether Waste into Organic Semiconductors by Carbon–Sulfur Bond Activation

2019 ◽  
Vol 58 (15) ◽  
pp. 5044-5048 ◽  
Author(s):  
Ting Zhu ◽  
Longfeng Jiang ◽  
Ying Li ◽  
Zengqi Xie ◽  
Zijie Li ◽  
...  
Keyword(s):  
Organic Semiconductors ◽  
Bond Activation ◽  
Sulfur Bond

Converting Thioether Waste into Organic Semiconductors by Carbon–Sulfur Bond Activation

2019 ◽  
Vol 131 (15) ◽  
pp. 5098-5102
Author(s):  
Ting Zhu ◽  
Longfeng Jiang ◽  
Ying Li ◽  
Zengqi Xie ◽  
Zijie Li ◽  
...  
Keyword(s):  
Organic Semiconductors ◽  
Bond Activation ◽  
Sulfur Bond

Carbon−Sulfur Bond Activation of Dibenzothiophenes and Phenoxythiin by [Rh(dippe)(μ-H)]2and [Rh2(dippe)2(μ-Cl)(μ-H)]†

2010 ◽  
Vol 29 (21) ◽  
pp. 4923-4931 ◽  
Author(s):  
Stephen S. Oster ◽  
Matthew R. Grochowski ◽  
Rene J. Lachicotte ◽  
William W. Brennessel ◽  
William D. Jones
Keyword(s):  
Bond Activation ◽  
Sulfur Bond

Sulfoxide Carbon−Sulfur Bond Activation

2005 ◽  
Vol 127 (12) ◽  
pp. 4180-4181 ◽  
Author(s):  
Joseph M. O'Connor ◽  
Kevin D. Bunker ◽  
Arnold L. Rheingold ◽  
Lev Zakharov
Keyword(s):  
Bond Activation ◽  
Sulfur Bond

Carbon–oxygen and carbon–sulfur bond activation of vinyl esters, ethers and sulfides by low valent ruthenium complexes †

2000 ◽  
pp. 2613-2625 ◽  
Author(s):  
Jose Giner Planas ◽  
Tsuyoshi Marumo ◽  
Yoichi Ichikawa ◽  
Masafumi Hirano ◽  
Sanshiro Komiya
Keyword(s):  
Bond Activation ◽  
Ruthenium Complexes ◽  
Vinyl Esters ◽  
Low Valent ◽  
Sulfur Bond

Palladium-catalyzed, unsymmetrical homocoupling of thiophenes via carbon–sulfur bond activation: a new avenue to homocoupling reactions

2017 ◽  
Vol 15 (37) ◽  
pp. 7830-7840
Author(s):  
Amir Hossein Vahabi ◽  
Abdolali Alizadeh ◽  
Hamid Reza Khavasi ◽  
Ayoob Bazgir
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Transition Metal Catalysis ◽  
Metal Catalysis ◽  
Palladium Catalyzed ◽  
Sulfur Bond

Introduction of an unprecedented pattern of reactivity, namely the C–N unsymmetrical homocoupling by joining the electrophilic and nucleophilic motifs of the substrate through transition-metal catalysis.

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