Steam Reforming of Alcohols from Biomass Conversion for H2Production

2015 ◽  
pp. 539-558
Author(s):  
Florence Epron ◽  
Nicolas Bion ◽  
Daniel Duprez ◽  
Catherine Batiot-Dupeyrat
Keyword(s):  
Steam Reforming ◽  
Biomass Conversion

Hydrogen Production From Waste and Renewable Resources

2021 ◽  
pp. 22-46
Author(s):  
Amit Kumar Chaurasia ◽  
Prasenjit Mondal
Keyword(s):  
Hydrogen Production ◽  
Steam Reforming ◽  
Energy Demand ◽  
Fossil Fuels ◽  
Biomass Conversion ◽  
Renewable Energy Resources ◽  
Rapid Urbanization ◽  
Research Attention ◽  
Toxic Emissions ◽  
Solar Conversion

Increasing population and rapid urbanization lead to degradation of the natural environment while waste generation and energy crisis are major challenges in the most developing country. Hydrogen is considered one of the most promising energy carriers and capable to replace fossil fuels and meet the world's energy demand and concomitantly reduce toxic emissions. Currently, the world produces around 50 million tonnes/year from the process (i.e., electrolysis of water, steam reforming of hydrocarbons, and auto-thermal processes), but these processes are not sustainable and economical due to energy requirements and waste/pollutants generation. These challenges required growing interest in renewable energy resources such as hydrogen as an energy carrier. Hydrogen production from renewable sources attracted recent research attention because of its potential for sustainability and diversity. Hydrogen can be produced by various thermal, chemical, and biological technologies that include steam reforming, electrolysis, biomass conversion, solar conversion, and biological conversion.

Technologies for Biomass Conversion

2006 ◽  
Author(s):  
Felicia Bucura ◽  
Violeta Niculescu ◽  
Elena David ◽  
Claudia Sisu ◽  
Marius Constantinescum
Keyword(s):  
Biomass Conversion

Pure Hydrogen Production from Steam Reforming of Bio-Sources

2015 ◽  
Vol 2 (2) ◽  
pp. 48-56 ◽  
Author(s):  
A. Iulianelli ◽  
◽  
G. Bagnato ◽  
A. Iulianelli ◽  
A. Vita Vita ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Steam Reforming ◽  
Pure Hydrogen

Ultra-Low Amounts of Palladium (0.005-0.05 Wt% Pd) Supported on Titania: Remarkable Low-Temperature Activity for NO Reduction with CO and Structure-Function Property Relationships in Methane Oxidation

2020 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Libor Kovarik ◽  
Nicholas R. Jaegers ◽  
János Szanyi ◽  
Yong Wang
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Methane Oxidation ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Oxide Reduction ◽  
Water Steam ◽  
Methane Steam ◽  
Anatase Titania ◽  
Nitric Oxide Reduction

<p>Atomically dispersed Pd +2 cations with ultra-dilute loading of palladium (0.005-0.05 wt%) were anchored on anatase titania and characterized with FTIR, microscopy and catalytic tests. CO infrared adsorption produces a sharp, narrow mono-carbonyl Pd(II)-CO band at ~2,130 cm<sup>-1</sup> indicating formation of highly uniform and stable Pd+2 ions on anatase titania. The 0.05 wt% Pd/TiO<sub>2</sub> sample was evaluated for methane combustion under dry and wet (industrially relevant) conditions in the presence and absence of carbon monoxide. Notably, we find the isolated palladium atoms respond dynamically upon oxygen concentration modulation (switching-on and switching off). When oxygen is removed from the wet methane stream, palladium ions are reduced to metallic state by methane and catalyze methane steam reforming instead of complete methane oxidation. Re-admission of oxygen restores Pd<sup>+2</sup> cations and switches off methane steam reforming activity. Moreover, 0.05 wt% Pd/TiO<sub>2</sub> is a competent CO oxidation catalyst in the presence of water steam with 90% CO conversion and TOF ~ 4,000 hr<sup>-1</sup> at 260 ⁰C. </p><p>More importantly, we find that diluting 0.05 wt% Pd/titania sample with titania to ultra-low 0.005 wt% palladium loading produces a remarkably active material for nitric oxide reduction with carbon monoxide under industrially relevant conditions with >90% conversion of nitric oxide at 180 ⁰C (~460 ppm NO and 150 L/g*hr flow rate in the presence of >2% water steam) and TOF ~6,000 hr<sup>-1</sup>. Pd thus outperforms state-of-the-art rhodium containing catalysts with (15-20 times higher rhodium loading; rhodium is ~ 3 times more expensive than palladium). Furthermore, palladium catalysts are more selective towards nitrogen and produce significantly less ammonia relative to the more traditional rhodium catalysts due to lower Pd amount nd lower water-gas-shift activity. Our study is the first example of utilizing ultra-low (0.05 wt% and less) noble metal (Pd) amounts to produce heterogeneous catalysts with extraordinary activity for nitric oxide reduction. This opens up a pathway to study other Pd, Pt and Rh containing materials with ultra-low loadings of expensive noble metals dispersed on titania or titania-coated oxides for industrially relevant nitric oxide abatement.</p>

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