Comprehensive kinetic model for the low temperature oxidation of hydrocarbons

AIChE Journal ◽  
1997 ◽  
Vol 43 (5) ◽  
pp. 1278-1286 ◽  
Author(s):  
Paolo Gaffuri ◽  
Tiziano Faravelli ◽  
Eliseo Ranzi ◽  
Nicholas P. Cernansky ◽  
David Miller ◽  
...  
Keyword(s):  
Low Temperature ◽  
Kinetic Model ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Hydrocarbons

Improved Kinetic Model of the Low-Temperature Oxidation ofn-Heptane

2014 ◽  
Vol 28 (11) ◽  
pp. 7178-7193 ◽  
Author(s):  
Matteo Pelucchi ◽  
Mattia Bissoli ◽  
Carlo Cavallotti ◽  
Alberto Cuoci ◽  
Tiziano Faravelli ◽  
...  
Keyword(s):  
Low Temperature ◽  
Kinetic Model ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation

Low-temperature oxidation and cool flames of propane

1954 ◽  
Vol 221 (1145) ◽  
pp. 151-170 ◽  
Keyword(s):  
Low Temperature ◽  
Thermal Instability ◽  
Analytical Study ◽  
Simple Explanation ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Cool Flame ◽  
Cool Flames ◽  
Oxidation Of Hydrocarbons ◽  
Flame Oxidation

A detailed analytical study of the cool-flame oxidation of propane has been carried out using a continuous-flow technique with a view to the further elucidation of the mechanism of the low-temperature oxidation of hydrocarbons. The formation of the three theoretically possible aldehydes has been demonstrated and the initially formed peroxide shown to be hydrogen peroxide. Measurements of the yields of the different products formed under varying conditions of temperature, composition and time of contact have been made and correlated with measurements of the luminous intensity and temperature of the flame. The results confirm the earlier conclusions of Norrish (1948) that aldehydes are the important branching agents in the temperature range of 300 to 400°C, and a detailed scheme based on that proposed earlier has been developed to account for the observations. The scheme has further been shown to allow of a simple explanation of the origin of the periodic character of the cool flame in terms of the thermal instability of the normal slow reaction.

Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons

2006 ◽  
Vol 251 (1-2) ◽  
pp. 8-23 ◽  
Author(s):  
Brian L. Conley ◽  
William J. Tenn ◽  
Kenneth J.H. Young ◽  
Somesh K. Ganesh ◽  
Steven K. Meier ◽  
...  
Keyword(s):  
Low Temperature ◽  
Low Temperature Oxidation ◽  
Homogeneous Catalysts ◽  
Temperature Oxidation ◽  
Oxidation Of Hydrocarbons
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