Fire Behavior of Raw Earth Bricks: Influence of Water Content and Cement Stabilization

This study focus on the effects of both water content and cement stabilization on the fire behavior of earth bricks. To observe the effect of cement stabilization, two materials are formulated: raw earth with only soil and water, and stabilized bricks with soil, water and cement (3.5% by mass of soil). Since the material’s mechanical strength can strongly influence its fire behavior, the raw bricks were compacted at 50 MPa to reach a compressive strength similar to the one of stabilized bricks. Four different water contents were tested; dry state obtained with oven drying and three others achieved through equalization at 50%, 75% and 100% of relative humidities. Bricks are then subjected to an ISO 834-1 standard fire. Results show that water content has caused a thermal instability behavior on the raw earth bricks after equalization at 50% and 75% relative humidities. Thermally stable bricks displayed a noticeable diffusion of cracks on their heated face. Furthermore, cement stabilization helps to prevent from thermal instabilities.

The Irradiation Instability of Protoplanetary Disks

The temperature in most parts of a protoplanetary disk is determined by irradiation from the central star. Numerical experiments of Watanabe and Lin suggested that such disks, also called “passive disks,” suffer from a thermal instability. Here we use analytical and numerical tools to elucidate the nature of this instability. We find that it is related to the flaring of the optical surface, the layer at which starlight is intercepted by the disk. Whenever a disk annulus is perturbed thermally and acquires a larger scale height, disk flaring becomes steeper in the inner part and flatter in the outer part. Starlight now shines more overhead for the inner part and so can penetrate into deeper layers; conversely, it is absorbed more shallowly in the outer part. These geometric changes allow the annulus to intercept more starlight, and the perturbation grows. We call this the irradiation instability. It requires only ingredients known to exist in realistic disks and operates best in parts that are both optically thick and geometrically thin (inside 30 au, but can extend to further reaches when, e.g., dust settling is considered). An unstable disk develops traveling thermal waves that reach order unity in amplitude. In thermal radiation, such a disk should appear as a series of bright rings interleaved with dark shadowed gaps, while in scattered light it resembles a moving staircase. Depending on the gas and dust responses, this instability could lead to a wide range of consequences, such as ALMA rings and gaps, dust traps, vertical circulation, vortices, and turbulence.

Two-terminal vertical thyristor using Schottky contact emitter to improve thermal instability

In a two-terminal-electrode vertical thyristor, the latch-up and latch-down voltages are decreased when the memory operation temperature of the memory cells increases, resulting in a severe reliability issue (i.e., thermal instability). This study fundamentally solves the thermal instability of a vertical-thyristor by achieving a cross-point memory-cell array using a vertical-thyristor with a structure of vertical n++-emitter, p+-base, n+-base, and p++-emitter. The vertical-thyristor using a Schottky contact metal emitter instead of an n++-Si emitter significantly improves the thermal stability between 293 and 373 K. Particularly, the improvement degree of the thermal stability is increased significantly with the use of the Schottky contact metal work function. Because the thermal instability (i.e., degree of latch-up voltage decrement vs. memory operation temperature) decreases with an increase in the Schottky contact metal work function, the dependency of the forward current density between the Schottky contact metal and p+-Si based on the memory operation temperature reduces with increase in the Schottky contact metal work function. Consequently, a higher Schottky contact metal work function produces a higher degree of improvement in the thermal stability, i.e., W (4.50 eV), Ti (4.33 eV), Ta (4.25 eV), and Al (4.12 eV). Further research on the fabrication process of a Schottky contact metal emitter vertical-thyristor is essential for the fabrication of a 3-D cross-point memory-cell.

Syntheses and Characterization of the First Cycloheptatrienyl Transition-Metal Complexes with a M-CF3 Bond

The organometallic chemistry of metal complexes with organocyclic ligands of higher than five hapticity is much more lacking than the chemistry of metal complexes with η5-cyclopentadienyl ligands, which has been explored in considerable depth, resulting in novel advances. The main reason for this is stability. In particular, reports indicate that (η7-C7H7)MLn complexes are considerably less stable than analogous (η5-C5H5)MLn. In perfluoroalkyl metal chemistry, there is currently no reported (η7-C7H7)MLn derivative, whereas a number of alkylated ones are known and important conclusions have been drawn about their stability. Responding to this void, and using Morrison’s trifluoromethylating reagent, the present study reports the synthesis and characterization of the first cycloheptatrienyl molybdenum complexes bearing the trifluoromethyl moiety; (η7-C7H7)Mo(CO)2CF3 (I), and (η7-C7H7)Mo(CO)(PMe3)CF3 (II) and discusses their low thermal instability.