A new mechanism for the low temperature oxidation of hydrocarbons in the gas phase

1965 ◽  
Vol 9 (3) ◽  
pp. 297-310 ◽  
Author(s):  
J.H. Knox
Keyword(s):  
Low Temperature ◽  
Gas Phase ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Hydrocarbons

Comprehensive kinetic model for the low temperature oxidation of hydrocarbons

AIChE Journal ◽  
1997 ◽  
Vol 43 (5) ◽  
pp. 1278-1286 ◽  
Author(s):  
Paolo Gaffuri ◽  
Tiziano Faravelli ◽  
Eliseo Ranzi ◽  
Nicholas P. Cernansky ◽  
David Miller ◽  
...  
Keyword(s):  
Low Temperature ◽  
Kinetic Model ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Hydrocarbons

Low-temperature oxidation and cool flames of propane

1954 ◽  
Vol 221 (1145) ◽  
pp. 151-170 ◽  
Keyword(s):  
Low Temperature ◽  
Thermal Instability ◽  
Analytical Study ◽  
Simple Explanation ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Cool Flame ◽  
Cool Flames ◽  
Oxidation Of Hydrocarbons ◽  
Flame Oxidation

A detailed analytical study of the cool-flame oxidation of propane has been carried out using a continuous-flow technique with a view to the further elucidation of the mechanism of the low-temperature oxidation of hydrocarbons. The formation of the three theoretically possible aldehydes has been demonstrated and the initially formed peroxide shown to be hydrogen peroxide. Measurements of the yields of the different products formed under varying conditions of temperature, composition and time of contact have been made and correlated with measurements of the luminous intensity and temperature of the flame. The results confirm the earlier conclusions of Norrish (1948) that aldehydes are the important branching agents in the temperature range of 300 to 400°C, and a detailed scheme based on that proposed earlier has been developed to account for the observations. The scheme has further been shown to allow of a simple explanation of the origin of the periodic character of the cool flame in terms of the thermal instability of the normal slow reaction.

scholarly journals The Sensitizing Effects of NOx on Methane Low-temperature Oxidation in a Jet Stirred Reactor

2018 ◽  
Vol 6 ◽  
Author(s):  
Lorena Marrodán Bretón ◽  
Yu Song ◽  
Nicolas Vin ◽  
Olivier Herbinet ◽  
Emmanuel Assaf ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Anaerobic Digestion ◽  
Low Temperature ◽  
Gas Phase ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
The Past ◽  
Oxidation Of Methane ◽  
Stirred Reactor

Biogas (mainly methane and carbon dioxide) produced from biomass anaerobic digestion is considered as a potential renewable gas-phase fuel. That is why the study of the mutual effects of CH4/NOx have attracted considerable attention in the past decade. In this work, the oxidation of methane with and without NOx addition has been investigated in a jet-stirred reactor.

Low-temperature oxidation of 2-butene in the gas phase

1968 ◽  
Vol 90 (25) ◽  
pp. 7176-7178 ◽  
Author(s):  
D. J. M. Ray ◽  
David J. Waddington
Keyword(s):  
Low Temperature ◽  
Gas Phase ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation
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