Models of High-Valent Intermediates of Non-Heme Diiron Alkane Monooxygenases: Electronic Structure of a Bis(μ-oxo)diron(IV) Complex with Locally Low-Spin Metal Centers

2004 ◽  
Vol 116 (7) ◽  
pp. 852-856
Author(s):  
Abhik Ghosh ◽  
Espen Tangen ◽  
Emmanuel Gonzalez ◽  
Lawrence Que
Keyword(s):  
Electronic Structure ◽  
Metal Centers ◽  
High Valent

scholarly journals Bystanding F+ Oxidants Enable Selective Reductive Elimination from High-Valent Metal Centers in Catalysis

2011 ◽  
Vol 50 (7) ◽  
pp. 1478-1491 ◽  
Author(s):  
Keary M. Engle ◽  
Tian-Sheng Mei ◽  
Xisheng Wang ◽  
Jin-Quan Yu
Keyword(s):  
Reductive Elimination ◽  
Metal Centers ◽  
High Valent

One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt(ii) carbene radical

2020 ◽  
Vol 56 (60) ◽  
pp. 8416-8419
Author(s):  
Amanda Grass ◽  
James A. Bellow ◽  
Gregory Morrison ◽  
Hans-Conrad zur Loye ◽  
Richard L. Lord ◽  
...  
Keyword(s):  
Electronic Structure ◽  
High Spin ◽  
Ligand Environment ◽  
Electron Reduction ◽  
High Valent

Synthesis, electronic structure, and reactivity of a novel Co(ii) carbene radical in the bis(alkoxide) ligand environment are reported.

Electronic Structure of N ‐Bridged High‐Valent Diiron‐Oxo

2019 ◽  
Vol 25 (54) ◽  
pp. 12491-12496 ◽  
Author(s):  
Quan Manh Phung ◽  
Kristine Pierloot
Keyword(s):  
Electronic Structure ◽  
High Valent

ChemInform Abstract: Bystanding F+ Oxidants Enable Selective Reductive Elimination from High-Valent Metal Centers in Catalysis

ChemInform ◽  
2011 ◽  
Vol 42 (22) ◽  
pp. no-no
Author(s):  
Keary M. Engle ◽  
Tian-Sheng Mei ◽  
Xisheng Wang ◽  
Jin-Quan Yu
Keyword(s):  
Reductive Elimination ◽  
Metal Centers ◽  
High Valent

Silyl Substitution Effects on Metal−Pentadienyl Bonding:  Synthesis, Structure, Photoelectron Spectroscopy, and Electronic Structure of a High-Valent Half-Open Zirconocene

2007 ◽  
Vol 26 (11) ◽  
pp. 2867-2871 ◽  
Author(s):  
Asha Rajapakshe ◽  
Rehan Basta ◽  
Atta M. Arif ◽  
Richard D. Ernst ◽  
Dennis L. Lichtenberger
Keyword(s):  
Electronic Structure ◽  
Photoelectron Spectroscopy ◽  
Substitution Effects ◽  
High Valent
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