Electronic Structure of Gallium, Copper, and Nickel Complexes of Corrole. High-Valent Transition Metal Centers versus Noninnocent Ligands

2000 ◽  
Vol 122 (21) ◽  
pp. 5100-5104 ◽  
Author(s):  
Abhik Ghosh ◽  
Tebikie Wondimagegn ◽  
Andreas B. J. Parusel
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Nickel Complexes ◽  
Metal Centers ◽  
High Valent

A look at periodic trends in d-block molecular electrocatalysts for CO2 reduction

2019 ◽  
Vol 48 (26) ◽  
pp. 9454-9468 ◽  
Author(s):  
Changcheng Jiang ◽  
Asa W. Nichols ◽  
Charles W. Machan
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Co2 Reduction ◽  
Metal Centers ◽  
Mononuclear Complexes ◽  
Research Activities ◽  
Group 6 ◽  
Group 10

Periodic trends in the electronic structure of the transition metal centers can be used to explain the observed CO2 reduction activities in molecular electrocatalysts for CO2 reductions. Research activities concerning both horizontal and vertical trends have been summarized with mononuclear complexes from Group 6 to Group 10.

Methane activation by ZSM-5-supported transition metal centers

2021 ◽  
Author(s):  
Daniyal Kiani ◽  
Sagar Sourav ◽  
Yadan Tang ◽  
Jonas Baltrusaitis ◽  
Israel E. Wachs
Keyword(s):  
Transition Metal ◽  
Methane Activation ◽  
Group V ◽  
Metal Centers ◽  
Methane Dehydroaromatization

The literature on methane dehydroaromatization (MDA) to benzene using ZSM-5 supported, group V–VIII transition metal-based catalysts (MOx/ZSM-5) is critically reviewed with a focus on in situ and operando molecular insights.

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