Shifting Chemical Equilibria in Flow-Efficient Decarbonylation Driven by Annular Flow Regimes

2014 ◽  
Vol 126 (43) ◽  
pp. 11741-11745 ◽  
Author(s):  
Bernhard Gutmann ◽  
Petteri Elsner ◽  
Toma Glasnov ◽  
Dominique M. Roberge ◽  
C. Oliver Kappe
2014 ◽  
Vol 53 (43) ◽  
pp. 11557-11561 ◽  
Author(s):  
Bernhard Gutmann ◽  
Petteri Elsner ◽  
Toma Glasnov ◽  
Dominique M. Roberge ◽  
C. Oliver Kappe

1998 ◽  
Vol 120 (1) ◽  
pp. 15-19 ◽  
Author(s):  
C. Kang ◽  
R. M. Vancko ◽  
A. S. Green ◽  
H. Kerr ◽  
W. P. Jepson

The effect of drag-reducing agents (DRA) on pressure gradient and flow regime has been studied in horizontal and 2-deg upward inclined pipes. Experiments were conducted for different flow regimes in a 10-cm i.d., 18-m long plexiglass system. The effectiveness of DRA was examined for concentrations ranging from 0 to 75 ppm. Studies were done for superficial liquid velocities between 0.03 and 1.5 m/s and superficial gas velocities between 1 and 14 m/s. The results indicate that DRA was effective in reducing the pressure gradients in single and multiphase flow. The DRA was more effective for lower superficial liquid and gas velocities for both single and multiphase flow. Pressure gradient reductions of up to 42 percent for full pipe flow, 81 percent for stratified flow, and 35 percent for annular flow were achieved in horizontal pipes. In 2 deg upward inclination, the pressure gradient reduction for slug flow, with a concentration of 50 ppm DRA, was found to be 28 and 38 percent at superficial gas velocities of 2 and 6 m/s, respectively. Flow regimes maps with DRA were constructed in horizontal pipes. Transition to slug flow with addition of DRA was observed to occur at higher superficial liquid velocities.


2017 ◽  
Vol 162 ◽  
pp. 309-321 ◽  
Author(s):  
E. Pagan ◽  
W.C. Williams ◽  
S. Kam ◽  
P.J. Waltrich

Volume 3 ◽  
2004 ◽  
Author(s):  
DuWayne Schubring ◽  
Timothy A. Shedd

In this study, non-intrusive pressure drop, liquid film thickness distribution and wave behavior measurements have been obtained for 140 and 220 two-phase flow conditions in horizontal 8.8 mm I.D and 15.1 mm I.D. tubes, respectively. Horizontal flow regimes ranging from stratified-wavy to annular were studied in long clear test sections. Pressure drop data appeared to show different trends for the wavy, wavy-annular and annular flow regimes, suggesting that a unique model may be required for each. In addition, wave frequency showed clearly different behavior for these regimes, with only minor liquid flow dependence in the wavy and wavy-annular flows and strong liquid flow dependence in annular flow. Interestingly, disturbance wave velocity could be correlated to within 10% by the gas friction velocity in the annular regime and within 20% in the wavy-annular regime, leading to a simple correlation between pressure drop and wave velocity. Base film thickness data (between waves) show that the film is relatively insensitive to gas flow at the side and top of the tube and that the film thickness around the tube becomes nearly independent of liquid flow rate at high gas flows. Empirical correlations of the various data sets are presented with the goal of aiding general horizontal two-phase flow modeling efforts.


Author(s):  
Srinivas Garimella

This paper presents an overview of the use of flow visualization in micro- and mini-channel geometries for the development of pressure drop and heat transfer models during condensation of refrigerants. Condensation flow mechanisms for round, square and rectangular tubes with hydraulic diameters in the range 1–5 mm for 0 < x < 1 and 150 kg/m2-s and 750 kg/m2-s were recorded using unique experimental techniques that permit flow visualization during the condensation process. The effect of channel shape and miniaturization on the flow regime transitions was documented. The flow mechanisms were categorized into four different flow regimes: intermittent flow, wavy flow, annular flow, and dispersed flow. These flow regimes were further subdivided into several flow patterns within each regime. It was observed that the intermittent and annular flow regimes become larger as the tube hydraulic diameter is decreased, at the expense of the wavy flow regime. These maps and transition lines can be used to predict the flow regime or pattern that will be established for a given mass flux, quality and tube geometry. These observed flow mechanisms, together with pressure drop measurements, are being used to develop experimentally validated models for pressure drop during condensation in each of these flow regimes for a variety of circular and noncircular channels with 0.4 < Dh < 5 mm. These flow regime-based models yield substantially better pressure drop predictions than the traditionally used correlations that are primarily based on air-water flows for large diameter tubes. Condensation heat transfer coefficients were also measured using a unique thermal amplification technique that simultaneously allows for accurate measurement of the low heat transfer rates over small increments of refrigerant quality and high heat transfer coefficients characteristic of microchannels. Models for these measured heat transfer coefficients are being developed using the documented flow mechanisms and the corresponding pressure drop models as the basis.


2012 ◽  
Vol 26 (7) ◽  
pp. 4067-4077 ◽  
Author(s):  
Geoffrey F. Hewitt

Author(s):  
N. R. Kesana ◽  
J. M. Throneberry ◽  
B. S. McLaury ◽  
S. A. Shirazi ◽  
E. F. Rybicki

Solid particle erosion is a mechanical process in which material is removed from a surface due to impacts of solid particles transported within a fluid. It is a common problem faced by the petroleum industry, as solid particles are also produced along with oil and gas. The erosion not only causes losses resulting from repairs and decreased production but also causes safety and environmental concerns. Therefore, the metal losses occurring in different multiphase flow patterns need to be studied and understood in order to develop protective guidelines for oil and gas production equipment. A large scale boom loop, which is capable of generating a wide variety of multiphase flow regimes was used for conducting experiments. Specifically, this work examines erosion measurements in multiphase slug and annular flow regimes. These flow regimes are selected since they produce higher metal losses than other flow regimes, and they also occur for a wide variety of operating conditions. Experiments are performed on a horizontal 0.0762 m (3-inch) diameter pipe, with superficial gas velocities ranging from 15.2 m/s (50 ft/s) to 45.7 m/s (150 ft/s) and superficial liquid velocities ranging from 0.46 m/s (1.5 ft/s) to 0.76 m/s (2.5 ft/s), for liquid viscosities of 1 cP and 10 cP. Carboxymethyl Cellulose (CMC) was used to increase the viscosity of the liquid without significantly altering the density of the liquid. Three different sand sizes (20, 150 and 300 micron sand) were used for performing tests. The shapes of the sand are also different with the 20 and 300 micron sand being sharper than the 150 micron sand. Erosion measurements are taken using Electrical Resistance (ER) probes which relate the change in electrical resistance to the change in the thickness of an exposed element resulting from erosion. Two probes are placed in a bend and another probe is placed in a straight section of pipe. The probes in the bend are flat-head probes, and they are placed flush with the outer wall in the 45 and 90 degree positions. The probe in the straight pipe is an angle-head probe which protrudes into the flow with the face placed in the center of the pipe. Under the flow conditions investigated, the angle-head probe measures the maximum erosion due to its placement. Results demonstrate a significant increase in the metal loss occurs when increasing the superficial gas velocity and decreasing the superficial liquid velocity. The effect of changing the viscosity of the liquid is not as clear. Results suggest a slight increase in metal loss by increasing the viscosity from 1cP to 10 cP in slug flow. However, for annular flow, higher erosion occurs for the lower liquid viscosity considered.


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