Rücktitelbild: Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides (Angew. Chem. 42/2016)

Potassium thiocyanate acts as an efficient sulfur surrogate in C–S cross-coupling reactions mediated by recyclable copper oxide nanoparticles under ligand free conditions. This protocol avoids foul smelling thiols, for the synthesis of a variety of symmetrical diaryl sulfides, via the cross-coupling of different aryl halides with potassium thiocyanate, affording corresponding products in moderate to excellent yields.

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Recent Progress in the Cross-Coupling Reaction Using Triorganosilyl-Type Reagents

Synlett ◽

10.1055/s-0036-1589008 ◽

2017 ◽

Vol 28 (15) ◽

pp. 1873-1884 ◽

Cited By ~ 6

Author(s):

Yasunori Minami ◽

Tamejiro Hiyama ◽

Takeshi Komiyama

Keyword(s):

Recent Progress ◽

Coupling Reaction ◽

Cross Coupling ◽

Aryl Halides ◽

Organosilicon Compounds ◽

Aryl Bromides ◽

Cross Coupling Reaction ◽

The Cross ◽

Silicon Based ◽

Coupling Polymerization

The silicon-based cross-coupling reaction has attracted much attention over recent decades because there are many advantages in using organosilicon compounds. However, the use of reagents with a triorganosilyl group as a key function remains to be established. This account summarizes our recent progress in cross-coupling chemistry with such silyl reagents.1 Introduction2 Preparation of HOMSi Reagents from Aryl Bromides and Disilanes3 HOMSi Reagents from Heteroaromatics and Hydrosilanes4 Cross-Coupling Polymerization with HOMSi Reagents5 Cross-Coupling with Aryl(triethyl)silanes6 Amination of Aryl Halides with N-TMS-Amines7 Conclusion and Perspective

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Rücktitelbild: Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides (Angew. Chem. 42/2016)

Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides

Back Cover: Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides (Angew. Chem. Int. Ed. 42/2016)

Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides

ChemInform Abstract: ASYMMETRIC NICKEL CATALYSIS IN THE CROSS-COUPLING REACTION OF ARYL HALIDES WITH GRIGNARD REAGENTS. A STUDY OF THE FACTORS INFLUENCING ASYMMETRIC INDUCTION

Asymmetric nickel catalysis in the cross-coupling reaction of aryl halides with grignard reagents. A study of the factors influencing asymmetric induction

Mechanistic studies of nickel catalysis in the cross coupling of aryl halides with alkylmetals. Role of arylalkylnickel(II) species as intermediates

ChemInform Abstract: MECHANISTIC STUDIES OF NICKEL CATALYSIS IN THE CROSS COUPLING OF ARYL HALIDES WITH ALKYLMETALS. ROLE OF ARYLALKYLNICKEL(II) SPECIES AS INTERMEDIATES

Generation of metalated thiophenes with Grignard reagent and catalytic secondary amine for the cross coupling reaction with aryl halides

Nano copper oxide catalyzed synthesis of symmetrical diaryl sulfides under ligand free conditions

Recent Progress in the Cross-Coupling Reaction Using Triorgano­silyl-Type Reagents

Recent Progress in the Cross-Coupling Reaction Using Triorganosilyl-Type Reagents