Synthesis of Pyrrolidines by a Csp 3 ‐Csp 3 /Csp 3 ‐ N Transition‐Metal‐Free Domino Reaction of Boronic Acids with γ‐Azido‐ N ‐Tosylhydrazones

2020 ◽  
Author(s):  
Lucía Florentino ◽  
Lucía López ◽  
Raquel Barroso ◽  
María‐Paz Cabal ◽  
Carlos Valdés
Keyword(s):  
Transition Metal ◽  
Boronic Acids ◽  
Domino Reaction ◽  
Metal Free

Synthesis of Pyrrolidines by a Csp 3 ‐Csp 3 /Csp 3 ‐ N Transition‐Metal‐Free Domino Reaction of Boronic Acids with γ‐Azido‐ N ‐Tosylhydrazones

2020 ◽  
Author(s):  
Lucía Florentino ◽  
Lucía López ◽  
Raquel Barroso ◽  
María‐Paz Cabal ◽  
Carlos Valdés
Keyword(s):  
Transition Metal ◽  
Boronic Acids ◽  
Domino Reaction ◽  
Metal Free

Transition metal-free approach to azafluoranthene scaffolds by aldol condensation/[1+2+3] annulation tandem reaction of isocyanoacetates with 8-(alkynyl)-1-naphthaldehydes

2021 ◽  
Author(s):  
Penghui Dong ◽  
Kashif Majeed ◽  
lingna Wang ◽  
Zijian Guo ◽  
Fengtao Zhou ◽  
...  
Keyword(s):  
Transition Metal ◽  
Aldol Condensation ◽  
Domino Reaction ◽  
Tandem Reaction ◽  
Metal Free ◽  
Successive Formation ◽  
General Synthesis

A transition metal-free aldol condensation/[1+2+3] annulation reaction of isocyanoacetates with 8-(alkynyl)-1-naphthaldehydes has been developed for the general synthesis of azafluoranthenes. This domino reaction enables successive formation of three new bonds...

Visible light-mediated transition metal-free esterification of amides with boronic acids

2020 ◽  
Vol 61 (43) ◽  
pp. 152444
Author(s):  
Hao Ding ◽  
Wan-Ying Qi ◽  
Jing-Song Zhen ◽  
Qiuping Ding ◽  
Yong Luo
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Boronic Acids ◽  
Metal Free

ChemInform Abstract: Ultrasound-Assisted, Transition-Metal-Free Synthesis of Diaryl Tellurides from Aryl Boronic Acids: A Possible Free-Radical Mechanism.

ChemInform ◽  
2015 ◽  
Vol 46 (10) ◽  
pp. no-no ◽  
Author(s):  
Balaji Mohan ◽  
Sori Hwang ◽  
Seongwan Jang ◽  
Kang Hyun Park
Keyword(s):  
Free Radical ◽  
Transition Metal ◽  
Boronic Acids ◽  
Radical Mechanism ◽  
Metal Free ◽  
Free Radical Mechanism ◽  
Ultrasound Assisted

Transition-Metal-Free, Intermolecular Azidoheteroarylation of Alkenes: Efficient Access to β-Azidoalkylated Quinoxalinones and Preliminary Antifungal Evaluation Against Magnaporthe grisea

Synthesis ◽  
2020 ◽  
Vol 52 (16) ◽  
pp. 2395-2409
Author(s):  
Weiwei Qin ◽  
Zhaodong Li ◽  
Yiming Du ◽  
Yue Chen ◽  
Yun-Lin Liu
Keyword(s):  
Transition Metal ◽  
Magnaporthe Grisea ◽  
Single Step ◽  
Domino Reaction ◽  
Efficient Synthesis ◽  
Metal Free ◽  
Efficient Access ◽  
First Time ◽  
Antibacterial Evaluation ◽  
Addition Pathway

An efficient, PhI(OAc)2-mediated, radical azidoheteroarylation of alkenes under transition-metal-free conditions is reported by employing TMSN3 and quinoxalin-2(1H)-ones as coupling partners. This domino reaction allows an efficient synthesis of valuable orangoazides containing quinoxalin-2(1H)-one derivatives and could be extended to phosphinyl-alkylated quinoxalin-2(1H)-one in a single step in moderate to excellent yields under mild conditions, as demonstrated by the preliminary antibacterial evaluation against Magnaporthe grisea for the first time. Mechanistic studies revealed that this transformation undergoes a cascade addition pathway controlled by a polar radical.

Transition-metal free reactions of boronic acids: cascade addition – ring-opening of furans towards functionalized γ-ketoaldehydes

2016 ◽  
Vol 52 (14) ◽  
pp. 3018-3021 ◽  
Author(s):  
S. Roscales ◽  
A. G. Csákÿ
Keyword(s):  
Transition Metal ◽  
Ring Opening ◽  
Boronic Acids ◽  
Metal Free

We describe the first ring-opening of furfuryl alcohols with boronic acids to afford functionalized γ-ketoaldehydes.

C–H Bond Formation with Boronic Acids and Derivatives by Transition-Metal-Free Conjugate Addition Reactions

Synthesis ◽  
2016 ◽  
Vol 48 (14) ◽  
pp. 2165-2177 ◽  
Author(s):  
Aurelio Csákÿ ◽  
Francisco Sánchez-Sancho
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Conjugate Addition ◽  
Boronic Acids ◽  
Addition Reactions ◽  
Metal Free

scholarly journals Transition‐Metal‐Free Coupling of 1,3‐Dipoles and Boronic Acids as a Sustainable Approach to C−C Bond Formation

2020 ◽  
Vol 26 (46) ◽  
pp. 10591-10597
Author(s):  
Keith Livingstone ◽  
Sophie Bertrand ◽  
Alan R. Kennedy ◽  
Craig Jamieson
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Boronic Acids ◽  
Metal Free
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