Enantioselective Total Synthesis of (+)-Homochelidonine by a PdII-Catalyzed Asymmetric Ring-Opening Reaction of ameso-Azabicyclic Alkene with an Aryl Boronic Acid

2007 ◽  
Vol 46 (3) ◽  
pp. 433-436 ◽  
Author(s):  
Helen A. McManus ◽  
Matthew J. Fleming ◽  
Mark Lautens
Keyword(s):  
Total Synthesis ◽  
Boronic Acid ◽  
Ring Opening ◽  
Enantioselective Total Synthesis ◽  
Ring Opening Reaction ◽  
Aryl Boronic Acid ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Asymmetric ring-opening of cyclopropyl ketones with β-naphthols catalyzed by a chiral N,N′-dioxide–scandium(iii) complex

2018 ◽  
Vol 5 (8) ◽  
pp. 1293-1296 ◽  
Author(s):  
Yong Xia ◽  
Fenzhen Chang ◽  
Lili Lin ◽  
Yali Xu ◽  
Xiaohua Liu ◽  
...  
Keyword(s):  
Ring Opening ◽  
Complex Catalyst ◽  
Ring Opening Reaction ◽  
Cyclopropyl Ketones ◽  
Naphthol Derivatives ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

An efficient asymmetric ring-opening reaction of cyclopropyl ketones with 2-naphthols has been realized using a chiral N,N′-dioxide–ScIII complex catalyst. A variety of chiral β-naphthol derivatives were obtained in excellent outcomes (up to 99% yield, 97% ee).

ChemInform Abstract: Palladium/Zinc Co-Catalyzed syn-Stereoselectively Asymmetric Ring-Opening Reaction of Oxabenzonorbornadienes with Phenols.

ChemInform ◽  
2015 ◽  
Vol 46 (43) ◽  
pp. no-no
Author(s):  
Sifeng Li ◽  
Jianbin Xu ◽  
Baomin Fan ◽  
Zhiwu Lu ◽  
Chaoyuan Zeng ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Reaction ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Palladium/Lewis Acid Cocatalyzed Reductive Asymmetric Ring-Opening Reaction of Azabenzonorbornadienes with Tertiary Amines as the Hydrogen Source

2018 ◽  
Vol 2018 (26) ◽  
pp. 3464-3470 ◽  
Author(s):  
Dapeng Zhang ◽  
Ruhima Khan ◽  
Fan Yang ◽  
Xuexin Zhang ◽  
Guoli Shen ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Ring Opening ◽  
Tertiary Amines ◽  
Ring Opening Reaction ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Palladium/Zinc Co-Catalyzedsyn-Stereoselectively Asymmetric Ring-Opening Reaction of Oxabenzonorbornadienes with Phenols

2015 ◽  
Vol 21 (25) ◽  
pp. 9003-9007 ◽  
Author(s):  
Sifeng Li ◽  
Jianbin Xu ◽  
Baomin Fan ◽  
Zhiwu Lu ◽  
Chaoyuan Zeng ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Reaction ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Sidearm as a Control in the Asymmetric Ring Opening Reaction of Donor-Acceptor Cyclopropane

2014 ◽  
Vol 32 (8) ◽  
pp. 669-672 ◽  
Author(s):  
Qikai Kang ◽  
Lijia Wang ◽  
Zhongbo Zheng ◽  
Junfang Li ◽  
Yong Tang
Keyword(s):  
Ring Opening ◽  
Ring Opening Reaction ◽  
Donor Acceptor ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening Reaction of Oxabenzonorbornadienes with Amines Using ZnI2as the Activator.

ChemInform ◽  
2016 ◽  
Vol 47 (26) ◽  
Author(s):  
Xin Xu ◽  
Jingchao Chen ◽  
Zhenxiu He ◽  
Yongyun Zhou ◽  
Baomin Fan
Keyword(s):  
Ring Opening ◽  
Ring Opening Reaction ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Asymmetric ring-opening reaction of azabenzonorbornadienes with phenols promoted by palladium/( R , R )-DIOP complex

Tetrahedron ◽  
2018 ◽  
Vol 74 (17) ◽  
pp. 2174-2181
Author(s):  
Zhen Xiu He ◽  
Yongyun Zhou ◽  
Baiqiu Han ◽  
Xin Xu ◽  
Yun Li ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Reaction ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Platinum-Catalyzed Asymmetric Ring-opening Reaction of Oxabenzonorbornadiene with Terminal Alkynes

2014 ◽  
Vol 32 (7) ◽  
pp. 613-618 ◽  
Author(s):  
Yuhua Long ◽  
Han Jiang ◽  
Zhifu Zou ◽  
Kaixuan Chen ◽  
Yali Fang
Keyword(s):  
Ring Opening ◽  
Terminal Alkynes ◽  
Ring Opening Reaction ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction
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