Chiral N-Heterocyclic Carbenes in Natural Product Synthesis: Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross-Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C

Dennis G. Gillingham; Amir H. Hoveyda

doi:10.1002/anie.200700501

Chiral N-Heterocyclic Carbenes in Natural Product Synthesis: Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross-Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C

Angewandte Chemie International Edition ◽

10.1002/anie.200700501 ◽

2007 ◽

Vol 46 (21) ◽

pp. 3860-3864 ◽

Cited By ~ 127

Author(s):

Dennis G. Gillingham ◽

Amir H. Hoveyda

Keyword(s):

Total Synthesis ◽

Natural Product ◽

Ring Opening ◽

Heterocyclic Carbenes ◽

Natural Product Synthesis ◽

Allylic Alkylation ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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Chiral N-Heterocyclic Carbenes in Natural Product Synthesis: Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross-Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C

Angewandte Chemie ◽

10.1002/ange.200700501 ◽

2007 ◽

Vol 119 (21) ◽

pp. 3934-3938 ◽

Cited By ~ 46

Author(s):

Dennis G. Gillingham ◽

Amir H. Hoveyda

Keyword(s):

Total Synthesis ◽

Natural Product ◽

Ring Opening ◽

Heterocyclic Carbenes ◽

Natural Product Synthesis ◽

Allylic Alkylation ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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Chiral N-Heterocyclic Carbenes in Natural Product Synthesis: Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross-Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C.

ChemInform ◽

10.1002/chin.200736208 ◽

2007 ◽

Vol 38 (36) ◽

Author(s):

Dennis G. Gillingham ◽

Amir H. Hoveyda

Keyword(s):

Total Synthesis ◽

Natural Product ◽

Ring Opening ◽

Heterocyclic Carbenes ◽

Natural Product Synthesis ◽

Allylic Alkylation ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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Efficient Enantioselective Synthesis of Piperidines through Catalytic Asymmetric Ring-Opening/Cross-Metathesis Reactions

Angewandte Chemie International Edition ◽

10.1002/anie.200605130 ◽

2007 ◽

Vol 46 (24) ◽

pp. 4534-4538 ◽

Cited By ~ 65

Author(s):

G. Alex Cortez ◽

Richard R. Schrock ◽

Amir H. Hoveyda

Keyword(s):

Ring Opening ◽

Enantioselective Synthesis ◽

Cross Metathesis ◽

Metathesis Reactions ◽

Catalytic Asymmetric ◽

Asymmetric Ring Opening

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Natural product synthesis via allylsilanes. 1. Synthesis and reactions of (1E,3E)-4-acetoxy-1-(trimethylsilyl)-1,3-butadiene and its use in the total synthesis of (.+-.)-shikimic acid

Journal of the American Chemical Society ◽

10.1021/ja00372a034 ◽

1982 ◽

Vol 104 (8) ◽

pp. 2308-2310 ◽

Cited By ~ 53

Author(s):

Masato Koreeda ◽

Marco A. Ciufolini

Keyword(s):

Total Synthesis ◽

Natural Product ◽

Shikimic Acid ◽

Natural Product Synthesis

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Tandem Asymmetric Ring-Opening/Cross Metathesis (AROM/CM) or Tandem Asymmetric Ring-Opening/Ring-Closing Metathesis (AROM/RCM)

Stereoselective Synthesis 1 ◽

10.1055/sos-sd-201-00431 ◽

2011 ◽

pp. 1

Author(s):

S. K. Collins

Keyword(s):

Ring Opening ◽

Ring Closing Metathesis ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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Combined coinage metal catalysis in natural product synthesis: total synthesis of (+)-varitriol and seven analogs

Organic & Biomolecular Chemistry ◽

10.1039/c2ob25069a ◽

2012 ◽

Vol 10 (30) ◽

pp. 5965 ◽

Cited By ~ 19

Author(s):

Tao Sun ◽

Carl Deutsch ◽

Norbert Krause

Keyword(s):

Total Synthesis ◽

Natural Product ◽

Natural Product Synthesis ◽

Metal Catalysis ◽

Coinage Metal

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Catalytic, Enantioselective Synthesis of 1,2-anti-Diols by Asymmetric Ring-Opening/Cross-Metathesis

Angewandte Chemie ◽

10.1002/ange.201310767 ◽

2014 ◽

Vol 126 (15) ◽

pp. 3966-3969 ◽

Cited By ~ 9

Author(s):

John Hartung ◽

Robert H. Grubbs

Keyword(s):

Ring Opening ◽

Enantioselective Synthesis ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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Catalytic, Enantioselective Synthesis of 1,2-anti-Diols by Asymmetric Ring-Opening/Cross-Metathesis

Angewandte Chemie International Edition ◽

10.1002/anie.201310767 ◽

2014 ◽

Vol 53 (15) ◽

pp. 3885-3888 ◽

Cited By ~ 30

Author(s):

John Hartung ◽

Robert H. Grubbs

Keyword(s):

Ring Opening ◽

Enantioselective Synthesis ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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Efficient Enantioselective Synthesis of Functionalized Tetrahydropyrans by Ru-Catalyzed Asymmetric Ring-Opening Metathesis/Cross-Metathesis (AROM/CM)

Journal of the American Chemical Society ◽

10.1021/ja0458672 ◽

2004 ◽

Vol 126 (39) ◽

pp. 12288-12290 ◽

Cited By ~ 102

Author(s):

Dennis G. Gillingham ◽

Osamu Kataoka ◽

Steven B. Garber ◽

Amir H. Hoveyda

Keyword(s):

Ring Opening ◽

Enantioselective Synthesis ◽

Cross Metathesis ◽

Asymmetric Ring Opening

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CatalyticZ-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis

Angewandte Chemie International Edition ◽

10.1002/anie.201302538 ◽

2013 ◽

Vol 52 (32) ◽

pp. 8395-8400 ◽

Cited By ~ 44

Author(s):

Tyler J. Mann ◽

Alexander W. H. Speed ◽

Richard R. Schrock ◽

Amir H. Hoveyda

Keyword(s):

Natural Product ◽

Natural Product Synthesis ◽

Cross Metathesis ◽

Allylic Ethers

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