Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E‐H Bonds

2021 ◽  
Author(s):  
Nikita M. Ankudinov ◽  
Denis A. Chusov ◽  
Yulia V. Nelyubina ◽  
Dmitry Perekalin
Keyword(s):  
Diazo Compounds ◽  
Rhodium Complexes ◽  
Diene Ligands

Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

2006 ◽  
Vol 71 (2) ◽  
pp. 197-206 ◽  
Author(s):  
Martin Pošta ◽  
Jan Čermák ◽  
Pavel Vojtíšek ◽  
Ivana Císařová
Keyword(s):  
Rhodium Complexes ◽  
Iridium Complexes ◽  
X Ray ◽  
First Time

The first rhodium complexes of diphosphinoazines [{RhCl(1,2-η:5,6-η-CH=CHCH2CH2CH=CHCH2CH2)}2 {μ-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.

scholarly journals Platinum and rhodium complexes ligated by imidazolium-substituted phosphine as efficient and recyclable catalysts for hydrosilylation

RSC Advances ◽  
2019 ◽  
Vol 9 (50) ◽  
pp. 29396-29404 ◽  
Author(s):  
Magdalena Jankowska-Wajda ◽  
Olga Bartlewicz ◽  
Andrea Szpecht ◽  
Adrian Zajac ◽  
Marcin Smiglak ◽  
...  
Keyword(s):  
Rhodium Complexes ◽  
Recyclable Catalysts ◽  
High Yields

Platinum and rhodium complexes ligated by imidazolium substituted phosphine were obtained with high yields and applied as efficient catalysts.

New catalysts for the reduction of aromatic diazo compounds by alcohols to hydrocarbons

1983 ◽  
Vol 32 (4) ◽  
pp. 858-861 ◽  
Author(s):  
V. S. Lenenko ◽  
A. P. Borisov ◽  
V. D. Makhaev ◽  
E. I. Mysov ◽  
V. B. Shur ◽  
...  
Keyword(s):  
Diazo Compounds

scholarly journals Low‐Temperature Intramolecular [4+2] Cycloaddition of Allenes with Arenes for the Synthesis of Diene Ligands

2020 ◽  
Author(s):  
Durga Prasad Hari ◽  
Guillaume Pisella ◽  
Matthew D. Wodrich ◽  
Artem V. Tsymbal ◽  
Farzaneh Fadaei Tirani ◽  
...  
Keyword(s):  
Low Temperature ◽  
Diene Ligands
Sign in / Sign up

Export Citation Format

Share Document