Synthesis of chiral polymers containing the acetoxybornyl group and their applications on the asymmetric induction

1992 ◽  
Vol 45 (9) ◽  
pp. 1587-1594 ◽  
Author(s):  
Jui-Hsiang Liu ◽  
Jue-Cheng Kuo ◽  
Mau-Ching Fang
2005 ◽  
Vol 70 (3) ◽  
pp. 361-369 ◽  
Author(s):  
Dušan Drahoňovský ◽  
Petr Štěpnička ◽  
Dalimil Dvořák

P-Chiral (S,RP)-2-{1'-[butyl(phenyl)phosphanyl]ferrocen-1-yl}-4-isopropyl-4,5-dihydrooxazole (6) and (S,SP)-2-{1'-[butyl(phenyl)phosphanyl]ferrocen-1-yl}-4-isopropyl-4,5-dihydrooxazole (7) were prepared by the procedure developed by Jugé, starting from enantiomerically pure (-)- or (+)-ephedrine and dichloro(phenyl)phosphine. Compounds 6 and 7 were examined for asymmetric induction in the Pd-catalyzed reaction of rac-1,3-diphenylallyl acetate with dimethyl malonate. The best results were obtained with 7 (98% ee), while 6 gave 82% ee.


ChemInform ◽  
2010 ◽  
Vol 25 (49) ◽  
pp. no-no
Author(s):  
Y. HASHIMOTO ◽  
Y. SATO ◽  
N. TAKESHITA ◽  
K. KUDO ◽  
K. SAIGO

ChemInform ◽  
2008 ◽  
Vol 39 (35) ◽  
Author(s):  
Yujiro Hayashi ◽  
Hirofumi Yamaguchi ◽  
Maya Toyoshima ◽  
Kotaro Okada ◽  
Takumi Toyo ◽  
...  

2003 ◽  
Vol 41 (21) ◽  
pp. 2744-2754 ◽  
Author(s):  
Kenneth D. Singer ◽  
Rolfe G. Petschek ◽  
Victor Ostroverkhov ◽  
Robert J. Twieg ◽  
Ludmilla Sukhomlinova

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