Nanostructured PZT synthesized from metal-polyvinyl alcohol gel: Studies on metal-polymer interaction

2008 ◽  
Vol 110 (5) ◽  
pp. 2693-2697 ◽  
Author(s):  
Subir Roy
Keyword(s):  
Polyvinyl Alcohol ◽  
Metal Polymer ◽  
Polymer Interaction

scholarly journals Characterization of metal‐polymer interaction forces by AFM for insert molding applications

2020 ◽  
Vol 60 (12) ◽  
pp. 3036-3045
Author(s):  
Hrushikesh Abhyankar ◽  
D. Patrick Webb ◽  
Geoff D. West ◽  
David A. Hutt
Keyword(s):  
Interaction Forces ◽  
Insert Molding ◽  
Metal Polymer ◽  
Polymer Interaction

Tailoring Dynamic Metal‐Polymer Interaction to Improve Catalyst Selectivity and Longevity in Hydrogenation

2021 ◽  
Author(s):  
Kyunglim Hyun ◽  
Younghwan Park ◽  
Songhyun Lee ◽  
Jueun Lee ◽  
Yeonwoo Choi ◽  
...  
Keyword(s):  
Catalyst Selectivity ◽  
Metal Polymer ◽  
Polymer Interaction

Tailoring a Dynamic Metal–Polymer Interaction to Improve Catalyst Selectivity and Longevity in Hydrogenation

2021 ◽  
Author(s):  
Kyunglim Hyun ◽  
Younghwan Park ◽  
Songhyun Lee ◽  
Jueun Lee ◽  
Yeonwoo Choi ◽  
...  
Keyword(s):  
Catalyst Selectivity ◽  
Metal Polymer ◽  
Polymer Interaction

scholarly journals Dynamic metal-polymer interaction for the design of chemoselective and long-lived hydrogenation catalysts

2020 ◽  
Vol 6 (28) ◽  
pp. eabb7369 ◽  
Author(s):  
Songhyun Lee ◽  
Seung-Jae Shin ◽  
Hoyong Baek ◽  
Yeonwoo Choi ◽  
Kyunglim Hyun ◽  
...  
Keyword(s):  
Catalyst Deactivation ◽  
Coke Formation ◽  
Inorganic Materials ◽  
Polyphenylene Sulfide ◽  
Partial Hydrogenation ◽  
Pd Catalysts ◽  
Hydrogenation Catalysts ◽  
Soft Engineering ◽  
Metal Polymer ◽  
Polymer Interaction

Metal catalysts are generally supported on hard inorganic materials because of their high thermochemical stabilities. Here, we support Pd catalysts on a thermochemically stable but “soft” engineering plastic, polyphenylene sulfide (PPS), for acetylene partial hydrogenation. Near the glass transition temperature (~353 K), the mobile PPS chains cover the entire surface of Pd particles via strong metal-polymer interactions. The Pd-PPS interface enables H2 activation only in the presence of acetylene that has a strong binding affinity to Pd and thus can disturb the Pd-PPS interface. Once acetylene is hydrogenated to weakly binding ethylene, re-adsorption of PPS on the Pd surface repels ethylene before it is further hydrogenated to ethane. The Pd-PPS interaction enables selective partial hydrogenation of acetylene to ethylene even in an ethylene-rich stream and suppresses catalyst deactivation due to coke formation. The results manifest the unique possibility of harnessing dynamic metal-polymer interaction for designing chemoselective and long-lived catalysts.

CHEMISTRY AND MICROSTRUCTURE AT METAL-POLYMER INTERFACES

1988 ◽  
Vol 49 (C5) ◽  
pp. C5-49-C5-59 ◽  
Author(s):  
P. S. HO ◽  
R. HAIGHT ◽  
R. C. WHITE ◽  
B. D. SILVERMAN
Keyword(s):  
Polymer Interfaces ◽  
Metal Polymer
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