Raman Spectra of Carbon Dioxide and Its Isotopic Variants in the Fermi Resonance Region: Part III. Analysis of Rovibrational Intensities for 12C16O2, 13C16O2, 12C18O2 and 12C16O18O

1982 ◽  
Vol 86 (9) ◽  
pp. 797-805 ◽  
Author(s):  
H. Finsterhölzl
Keyword(s):  
Carbon Dioxide ◽  
Raman Spectra ◽  
Resonance Region ◽  
Fermi Resonance

Raman Spectra of Carbon Dioxide and its Isotopic Variants in the Fermi Resonance Region: II. 12C18O2

1978 ◽  
Vol 32 (4) ◽  
pp. 401-402 ◽  
Author(s):  
H. W. Klöckner ◽  
H. Finsterhölzl ◽  
K. Srinivasan ◽  
H. W. Schrötter
Keyword(s):  
Carbon Dioxide ◽  
Raman Spectra ◽  
Resonance Region ◽  
Fermi Resonance ◽  
Region Ii

A study of the Raman spectra of alkanes in the Fermi-resonance region

2004 ◽  
Vol 708 (1-3) ◽  
pp. 189-195 ◽  
Author(s):  
N.A. Atamas ◽  
A.M. Yaremko ◽  
T. Seeger ◽  
A. Leipertz ◽  
A. Bienko ◽  
...  
Keyword(s):  
Raman Spectra ◽  
Resonance Region ◽  
Fermi Resonance

DENSITY EFFECTS IN THE RAMAN SPECTRUM OF CARBON DIOXIDE

1952 ◽  
Vol 30 (2) ◽  
pp. 99-110 ◽  
Author(s):  
H. L. Welsh ◽  
P. E. Pashler ◽  
B. P. Stoicheff
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Raman Spectrum ◽  
Relative Intensity ◽  
Intermolecular Forces ◽  
Anisotropic Scattering ◽  
Fermi Resonance ◽  
Intensity Effect ◽  
Density Effects ◽  
Frequency Changes

Two Raman tubes, one of quartz and one of glass, capable of withstanding pressures up to 75 and 300 atm. respectively, were used to study density effects in the Raman spectrum of carbon dioxide. The components of the ν1 band show changes in frequency and relative intensity with increasing density. An analysis shows that the frequency changes are due to a lowering of the frequency of 2ν2, in Fermi resonance with ν1, with increasing density. The intensity effect, however, is not completely explained by the change in the sharpness of the resonance. In the high pressure gas and in the liquid faint bands corresponding to the Raman inactive frequencies, ν2 and ν3, are observed. The effect of increasing density on the rotational Raman spectrum can be explained in terms of the broadening of anisotropic scattering by intermolecular forces.

On Fermi resonance in carbon dioxide

1965 ◽  
Vol 16 (2) ◽  
pp. 278-290 ◽  
Author(s):  
G. Amat ◽  
M. Pimbert
Keyword(s):  
Carbon Dioxide ◽  
Fermi Resonance

Fermi resonance in Raman spectra of crystalline 5-aminotetrazole monohydrate

1984 ◽  
Vol 15 (4) ◽  
pp. 232-236 ◽  
Author(s):  
Adriano Bigotto ◽  
Gianna Castellani
Keyword(s):  
Raman Spectra ◽  
Fermi Resonance
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