The Debye-Hückel Theory for Hydrated Ions. V. Enthalpy of Aqueous Solutions of Alkali Halides at 25°C

1993 ◽  
Vol 97 (1) ◽  
pp. 64-69
Author(s):  
HansjüRgen Schönert
1978 ◽  
Vol 56 (1) ◽  
pp. 24-28 ◽  
Author(s):  
Alain Roux ◽  
Goolam M. Musbally ◽  
Gérald Perron ◽  
Jacques E. Desnoyers ◽  
Prem Paul Singh ◽  
...  

Measurements at 25 °C with flow calorimeters and densimeters have led to heat capacities and densities of aqueous solutions of 11 1:1 electrolytes: NaClO3, NaBrO3, NaIO3, NaNO3, NaClO4, NH4NO3, KClO3, KBrO3, KIO3, NH4Cl, and NH4ClO4. The first 6 salts were studied up to near saturation. We have used results of these measurements to obtain apparent molal heat capacities and apparent molal volumes of the various solutes. Extrapolation to infinite dilution on the basis of the Debye–Hückel theory bas led to [Formula: see text]and [Formula: see text] values for each solute. We have compared these standard values with results of earlier investigations.


1969 ◽  
Vol 16 (5) ◽  
pp. 421-439 ◽  
Author(s):  
C. Deverell ◽  
R.E. Richards

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