Reactivity of the Heavier Group-13 Monochlorides [{CH(SiMe3)2}2AlCl], InCl, TlCl, and of the Elements Ga and Hg Towards the Unsupported Ni-Ni Bond of [{(η5-Cp)Ni(PEt3)}2] — A Straightforward Synthetic Approach to the Synthesis of Mixed Main-Group/Transition-Metal Clusters Containing Unsupported Metal-Metal Bonds

1997 ◽  
Vol 130 (10) ◽  
pp. 1433-1440 ◽  
Author(s):  
Jörg J. Schneider ◽  
Uwe Denninger ◽  
Jörg Hagen ◽  
Carl Krüger ◽  
Dieter Bläser ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Clusters ◽  
Main Group ◽  
Synthetic Approach ◽  
Transition Metal Clusters ◽  
Group 13 ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Group 13 Metal-Metal Bonds

2015 ◽  
pp. 455-484 ◽  
Author(s):  
Joseph A.B. Abdalla ◽  
Simon Aldridge
Keyword(s):  
Group 13 ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Novel routes to heteronuclear metal clusters containing rhodium

1982 ◽  
Vol 308 (1501) ◽  
pp. 87-93 ◽  
Keyword(s):  
Similar Pattern ◽  
Metal Clusters ◽  
Frontier Orbitals ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds ◽  
Metal Ligand

Logical methods for preparing small metal clusters with heteronuclear metal-metal bonds can be devised by appreciating the isolobal relationships that exist between certain metal ligand combinations and organic fragments. Thus the group W(CO) 2 (r|-C 5 H 5 ) has frontier orbitals of similar pattern to those of CH, while those of Rh(CO) (r|-C 5 Me 5 ) and CH 2 are also similar. This paper shows how such ideas have been employed to generate compounds with bonds between rhodium and other metals.

scholarly journals Mixed main group transition metal clusters: Reactions of [Ru 3 (CO) 10 (μ-dppm)] with Ph 3 SnH

2017 ◽  
Vol 840 ◽  
pp. 47-55 ◽  
Author(s):  
Md. Mehedi M. Khan ◽  
Shishir Ghosh ◽  
Graeme Hogarth ◽  
Derek A. Tocher ◽  
Michael G. Richmond ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Clusters ◽  
Main Group ◽  
Transition Metal Clusters
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