Anion-Cation Cooperative Catalysis by Ionic Liquids

ChemCatChem ◽  
2011 ◽  
Vol 3 (8) ◽  
pp. 1359-1364 ◽  
Author(s):  
Lifeng Zhang ◽  
Xianlei Fu ◽  
Guohua Gao
RSC Advances ◽  
2016 ◽  
Vol 6 (39) ◽  
pp. 33048-33054 ◽  
Author(s):  
Qun-xing Luo ◽  
Min Ji ◽  
Sang-Eon Park ◽  
Ce Hao ◽  
Yan-qin Li

PdCl2 immobilized on CuBTC with the aid of ILs shows an enhanced catalytic performance in cyclohexene oxidation due to Pd–Cu cooperative catalysis and stabilization of Pd(ii).


2016 ◽  
Vol 12 ◽  
pp. 1911-1924 ◽  
Author(s):  
Maurizio Selva ◽  
Alvise Perosa ◽  
Sandro Guidi ◽  
Lisa Cattelan

The use of ionic liquids (ILs) as organocatalysts is reviewed for transesterification reactions, specifically for the conversion of nontoxic compounds such as dialkyl carbonates to both linear mono-transesterification products or alkylene carbonates. An introductory survey compares pros and cons of classic catalysts based on both acidic and basic systems, to ionic liquids. Then, innovative green syntheses of task-specific ILs and their representative applications are introduced to detail the efficiency and highly selective outcome of ILs-catalyzed transesterification reactions. A mechanistic hypothesis is discussed by the concept of cooperative catalysis based on the dual (electrophilic/nucleophilic) activation of reactants.


2011 ◽  
pp. 110923034559006
Author(s):  
Arnd Garsuch ◽  
D. Michael Badine ◽  
Klaus Leitner ◽  
Luiz H. S. Gasparotto ◽  
Natalia Borisenko ◽  
...  

2020 ◽  
Vol 42 (3) ◽  
pp. 218-225
Author(s):  
T.T. Alekseeva ◽  
◽  
N.V. Kozak ◽  
N.V. Yarova ◽  
◽  
...  
Keyword(s):  

2016 ◽  
Vol 13 (1) ◽  
pp. 53
Author(s):  
Siti Nabihah Jamaludin ◽  
Ruzitah Mohd Salleh

Anthropogenic CO2 emissions has led to global climate change and widely contributed to global warming since its concentration has been increasing over time. It has attracted vast attention worldwide. Currently, the different CO2 capture technologies available include absorption, solid adsorption and membrane separation. Chemical absorption technology is regarded as the most mature technology and is commercially used in the industry. However, the key challenge is to find the most efficient solvent in capturing CO2. This paper reviews several types of CO2 capture technologies and the various factors influencing the CO2 absorption process, resulting in the development of a novel solvent for CO2 capture.


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