Mesoporous Silicas as Versatile Supports to Tune the Palladium-Catalyzed Selective Aerobic Oxidation of Allylic Alcohols

ChemCatChem ◽  
2012 ◽  
Vol 5 (4) ◽  
pp. 939-950 ◽  
Author(s):  
Christopher M. A. Parlett ◽  
Duncan W. Bruce ◽  
Nicole S. Hondow ◽  
Mark A. Newton ◽  
Adam F. Lee ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Mesoporous Silicas ◽  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Selective Aerobic Oxidation

scholarly journals Inside Cover: Mesoporous Silicas as Versatile Supports to Tune the Palladium-Catalyzed Selective Aerobic Oxidation of Allylic Alcohols (ChemCatChem 4/2013)

ChemCatChem ◽  
2013 ◽  
Vol 5 (4) ◽  
pp. 826-826
Author(s):  
Christopher M. A. Parlett ◽  
Duncan W. Bruce ◽  
Nicole S. Hondow ◽  
Mark A. Newton ◽  
Adam F. Lee ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Mesoporous Silicas ◽  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Selective Aerobic Oxidation

High-Activity, Single-Site Mesoporous Pd/Al2O3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols

2007 ◽  
Vol 119 (45) ◽  
pp. 8747-8750 ◽  
Author(s):  
Simon F. J. Hackett ◽  
Rik M. Brydson ◽  
Mhairi H. Gass ◽  
Ian Harvey ◽  
Andrew D. Newman ◽  
...  
Keyword(s):  
High Activity ◽  
Aerobic Oxidation ◽  
Single Site ◽  
Allylic Alcohols ◽  
Selective Aerobic Oxidation

Practical organic solvent-free Cu(OAc)2/DMAP/TEMPO-catalyzed aldehyde and imine formation from alcohols under air atmosphere

RSC Advances ◽  
2014 ◽  
Vol 4 (90) ◽  
pp. 48777-48782 ◽  
Author(s):  
Mingyu Guan ◽  
Chao Wang ◽  
Jingyu Zhang ◽  
Yingsheng Zhao
Keyword(s):  
Organic Solvent ◽  
Aerobic Oxidation ◽  
Ambient Air ◽  
Catalyst System ◽  
Solvent Free ◽  
Allylic Alcohols ◽  
Highly Efficient ◽  
Air Atmosphere ◽  
Selective Aerobic Oxidation

A highly efficient and practical organic solvent-free Cu(OAc)2/DMAP/TEMPO catalyst system for the selective aerobic oxidation of benzylic and allylic alcohols to aldehydes and phenones under an ambient air atmosphere was reported.

Selective Aerobic Oxidation of Allylic Alcohols to Carbonyl Compounds Using Catalytic Pd(OAc)2: High Intramolecular Selectivity

Synlett ◽  
2007 ◽  
Vol 2007 (12) ◽  
pp. 1869-1872 ◽  
Author(s):  
Fabienne Fache ◽  
Frédéric Batt ◽  
Emmanuel Bourcet ◽  
Youssef Kassab
Keyword(s):  
Carbonyl Compounds ◽  
Aerobic Oxidation ◽  
Allylic Alcohols ◽  
Selective Aerobic Oxidation

High-Activity, Single-Site Mesoporous Pd/Al2O3Catalysts for Selective Aerobic Oxidation of Allylic Alcohols

2007 ◽  
Vol 46 (45) ◽  
pp. 8593-8596 ◽  
Author(s):  
Simon F. J. Hackett ◽  
Rik M. Brydson ◽  
Mhairi H. Gass ◽  
Ian Harvey ◽  
Andrew D. Newman ◽  
...  
Keyword(s):  
High Activity ◽  
Aerobic Oxidation ◽  
Single Site ◽  
Allylic Alcohols ◽  
Selective Aerobic Oxidation

Metal-TUD-1 Catalyzed Aerobic Oxidation of Cyclohexane: A Comparative Study

2009 ◽  
Vol 62 (4) ◽  
pp. 360 ◽  
Author(s):  
Ramanathan Anand ◽  
Mohamed S. Hamdy ◽  
Rudy Parton ◽  
Thomas Maschmeyer ◽  
Jacobus C. Jansen ◽  
...  
Keyword(s):  
Comparative Study ◽  
Aerobic Oxidation ◽  
Structure Type ◽  
Relative Performance ◽  
Mesoporous Silicas ◽  
Metal Type ◽  
Tert Butylhydroperoxide ◽  
Selective Aerobic Oxidation ◽  
Subsequent Decomposition

The relative performance of various metal-incorporated mesoporous silicas of the TUD-1 structure type (M-TUD-1, where M = Ti, Cr, Co, Fe, Cu, Mn) in the selective aerobic oxidation of cyclohexane with tert-butylhydroperoxide and cyclohexylhydroperoxide (CHHP) to the respective hydroperoxides and subsequent decomposition to the alcohol and ketone is reported. In particular, relationships regarding metal type and loading, silica structure type and peroxide initiator are elucidated, to show that it is possible to tune catalysts for either CHHP formation or CHHP decomposition.

Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

2018 ◽  
Vol 8 (23) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xu Jin ◽  
Rengui Li ◽  
Yue Zhao ◽  
Xiaodan Liu ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Spatial Separation ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

2020 ◽  
Vol 59 (46) ◽  
pp. 20394-20398
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Yao Ge ◽  
Weiheng Huang ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Dicarboxylic Acids ◽  
Allylic Alcohols ◽  
Selective Synthesis ◽  
Palladium Catalyzed
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