Practical organic solvent-free Cu(OAc)2/DMAP/TEMPO-catalyzed aldehyde and imine formation from alcohols under air atmosphere

RSC Advances ◽  
2014 ◽  
Vol 4 (90) ◽  
pp. 48777-48782 ◽  
Author(s):  
Mingyu Guan ◽  
Chao Wang ◽  
Jingyu Zhang ◽  
Yingsheng Zhao
Keyword(s):  
Organic Solvent ◽  
Aerobic Oxidation ◽  
Ambient Air ◽  
Catalyst System ◽  
Solvent Free ◽  
Allylic Alcohols ◽  
Highly Efficient ◽  
Air Atmosphere ◽  
Selective Aerobic Oxidation

A highly efficient and practical organic solvent-free Cu(OAc)2/DMAP/TEMPO catalyst system for the selective aerobic oxidation of benzylic and allylic alcohols to aldehydes and phenones under an ambient air atmosphere was reported.

High-Activity, Single-Site Mesoporous Pd/Al2O3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols

2007 ◽  
Vol 119 (45) ◽  
pp. 8747-8750 ◽  
Author(s):  
Simon F. J. Hackett ◽  
Rik M. Brydson ◽  
Mhairi H. Gass ◽  
Ian Harvey ◽  
Andrew D. Newman ◽  
...  
Keyword(s):  
High Activity ◽  
Aerobic Oxidation ◽  
Single Site ◽  
Allylic Alcohols ◽  
Selective Aerobic Oxidation

A highly efficient palladium(ii)/polyoxometalate catalyst system for aerobic oxidation of alcohols

2015 ◽  
Vol 5 (3) ◽  
pp. 1428-1432 ◽  
Author(s):  
Laura M. Dornan ◽  
Mark J. Muldoon
Keyword(s):  
Aerobic Oxidation ◽  
Catalyst System ◽  
Phosphomolybdic Acid ◽  
Highly Efficient ◽  
Oxidation Of Alcohols

A simple catalyst system composed of Pd(OAc)2, phosphomolybdic acid and tetrabutylammonium acetate oxidises a range of alcohols efficiently, with turnover numbers (TONs) of up to 10 000.

Nicotine-derived ammonium salts as highly efficient catalysts for chemical fixation of carbon dioxide into cyclic carbonates under solvent-free conditions

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61179-61183 ◽  
Author(s):  
Abdol R. Hajipour ◽  
Yasaman Heidari ◽  
Gholamreza Kozehgary
Keyword(s):  
Carbon Dioxide ◽  
Organic Solvent ◽  
Solvent Free ◽  
Ammonium Salts ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Highly Efficient ◽  
Solvent Free Conditions ◽  
Recyclable Catalysts ◽  
Fixation Of Carbon Dioxide

Ammonium salts based on nicotine proved to be highly efficient and recyclable catalysts for the synthesis of cyclic carbonates from epoxides and CO2 without the utilization of any organic solvent and any additives.

Supported task-specific ionic liquid catalyst for highly efficient and recyclable aerobic oxidation of benzyl alcohols

2011 ◽  
Vol 89 (1) ◽  
pp. 68-71 ◽  
Author(s):  
Lin Liu ◽  
Juanjuan Ma ◽  
Zhen Sun ◽  
Jianping Zhang ◽  
Jingjing Huang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Aerobic Oxidation ◽  
Copper Salt ◽  
High Conversion ◽  
Allylic Alcohols ◽  
Benzyl Alcohols ◽  
Highly Efficient ◽  
Silica Supports ◽  
Task Specific Ionic Liquid

A novel catalytic system was prepared by impregnating ionic liquid immobilized 2,2,6,6-tetramethylpiperidyl-1-oxyl (TEMPO) and copper salt onto various silica supports. This catalytic system was capable of rapidly converting different benzylic and allylic alcohols into the corresponding aldehydes under O2 atmosphere with high conversion. Recycling results showed that the catalyst could be easily recovered and reused.

Mesoporous Silicas as Versatile Supports to Tune the Palladium-Catalyzed Selective Aerobic Oxidation of Allylic Alcohols

ChemCatChem ◽  
2012 ◽  
Vol 5 (4) ◽  
pp. 939-950 ◽  
Author(s):  
Christopher M. A. Parlett ◽  
Duncan W. Bruce ◽  
Nicole S. Hondow ◽  
Mark A. Newton ◽  
Adam F. Lee ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Mesoporous Silicas ◽  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Selective Aerobic Oxidation
Sign in / Sign up

Export Citation Format

Share Document