scholarly journals Insights on “nitrate salt” in lithium anode for stabilized solid electrolyte interphase

Carbon Energy ◽  
2022 ◽  
Author(s):  
Lin Fu ◽  
Xiancheng Wang ◽  
Zihe Chen ◽  
Yuanjian Li ◽  
Eryang Mao ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Nitrate Salt ◽  
Lithium Anode

scholarly journals Mastering the interface for advanced all-solid-state lithium rechargeable batteries

2016 ◽  
Vol 113 (47) ◽  
pp. 13313-13317 ◽  
Author(s):  
Yutao Li ◽  
Weidong Zhou ◽  
Xi Chen ◽  
Xujie Lü ◽  
Zhiming Cui ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Rechargeable Batteries ◽  
Ion Conductivity ◽  
Rhombohedral Structure ◽  
Interfacial Resistance ◽  
Lithium Anode ◽  
Metal Anode ◽  
Li Ion

A solid electrolyte with a high Li-ion conductivity and a small interfacial resistance against a Li metal anode is a key component in all-solid-state Li metal batteries, but there is no ceramic oxide electrolyte available for this application except the thin-film Li-P oxynitride electrolyte; ceramic electrolytes are either easily reduced by Li metal or penetrated by Li dendrites in a short time. Here, we introduce a solid electrolyte LiZr2(PO4)3 with rhombohedral structure at room temperature that has a bulk Li-ion conductivity σLi = 2 × 10−4 S⋅cm−1 at 25 °C, a high electrochemical stability up to 5.5 V versus Li+/Li, and a small interfacial resistance for Li+ transfer. It reacts with a metallic lithium anode to form a Li+-conducting passivation layer (solid-electrolyte interphase) containing Li3P and Li8ZrO6 that is wet by the lithium anode and also wets the LiZr2(PO4)3 electrolyte. An all-solid-state Li/LiFePO4 cell with a polymer catholyte shows good cyclability and a long cycle life.

A functional SrF2 coated separator enabling a robust and dendrite-free solid electrolyte interphase on a lithium metal anode

2019 ◽  
Vol 7 (37) ◽  
pp. 21349-21361 ◽  
Author(s):  
Xing Li ◽  
Yang Liu ◽  
Yong Pan ◽  
Mingshan Wang ◽  
Junchen Chen ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Lithium Anode ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Coated Separator

An SrF2 microsphere layer on a separator could be involved in SEI formation and result in a dendrite free SEI on a lithium anode.

Artificial Single-Ion Conducting Polymer Solid Electrolyte Interphase Layer toward Highly Stable Lithium Anode

2021 ◽  
Vol 4 (1) ◽  
pp. 862-869
Author(s):  
Jianwei Zhang ◽  
Yunyun Zhong ◽  
Shuanjin Wang ◽  
Dongmei Han ◽  
Min Xiao ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Conducting Polymer ◽  
Solid Electrolyte Interphase ◽  
Interphase Layer ◽  
Lithium Anode ◽  
Ion Conducting ◽  
Ion Conducting Polymer

Theoretical formulation of Li3a+bNaXb (X = halogen) as a potential artificial solid electrolyte interphase (ASEI) to protect the Li anode

2020 ◽  
Vol 22 (23) ◽  
pp. 12918-12928
Author(s):  
Junwu Sang ◽  
Yuran Yu ◽  
Zhuo Wang ◽  
Guosheng Shao
Keyword(s):  
Energy Density ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Solid Electrolyte Interphase ◽  
High Energy ◽  
High Energy Density ◽  
Li Ion Batteries ◽  
Theoretical Formulation ◽  
Lithium Anode ◽  
Li Ion

A major problem against the realization of high energy density and safe solid Li-ion batteries lies in detrimental reactions at the interface between the lithium anode and the solid electrolytes.

Shielding Polysulfide Intermediates by an Organosulfur‐Containing Solid Electrolyte Interphase on the Lithium Anode in Lithium–Sulfur Batteries

2020 ◽  
Vol 32 (37) ◽  
pp. 2003012 ◽  
Author(s):  
Jun‐Yu Wei ◽  
Xue‐Qiang Zhang ◽  
Li‐Peng Hou ◽  
Peng Shi ◽  
Bo‐Quan Li ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Lithium Anode ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

Solid electrolyte interphase formation by propylene carbonate reduction for lithium anode

2017 ◽  
Vol 19 (42) ◽  
pp. 28772-28780 ◽  
Author(s):  
Qinlai Qian ◽  
Yifu Yang ◽  
Huixia Shao
Keyword(s):  
Solid Electrolyte ◽  
Propylene Carbonate ◽  
Solid Electrolyte Interphase ◽  
Scanning Electrochemical Microscopy ◽  
Lithium Anode ◽  
Electrochemical Microscopy

The reduction of PC occurs in two potential stages which was explored by scanning electrochemical microscopy.

An oxygen-blocking oriented multifunctional solid-electrolyte interphase as protective layer for lithium metal anode in lithium–oxygen batteries

2020 ◽  
Author(s):  
Xiaodong Lin ◽  
Yu Gu ◽  
Xiao-Ru Shen ◽  
Wei-Wei Wang ◽  
Yu-Hao Hong ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Protective Layer ◽  
Lithium Metal ◽  
Lithium Anode ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Oxygen Batteries

For a period of time, the O2 cathode has been the focus of the researches, while the study on lithium anode and their interactions is quite rare in rechargeable lithium-oxygen...

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