Polyfunctional Lewis Acids: Intriguing Solid-State Structure and Selective Detection and Discrimination of Nitroaromatic Explosives

A reduced Schiff base used as a fluorescence chemo-sensor for selective detection of zinc(ii). Strong fluorescence behaviors of two zinc(ii) complexes are correlated with the presence of a rigid hydrogen-bonded network in their solid state structure.

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Tridentate Lewis-acids based on triphenylsilane

Dalton Transactions ◽

10.1039/c6dt04293g ◽

2017 ◽

Vol 46 (5) ◽

pp. 1645-1659 ◽

Cited By ~ 11

Author(s):

Janek Tomaschautzky ◽

Beate Neumann ◽

Hans-Georg Stammler ◽

Andreas Mix ◽

Norbert W. Mitzel

Keyword(s):

Solid State ◽

Lewis Acids ◽

Building Blocks ◽

State Structure ◽

Solid State Structure ◽

Guest Chemistry

Triphenylsilanes are versatile propeller-shaped building blocks and have been used for the syntheses of several novel poly-Lewis-acids. The first solid-state structure of a bisma-silatriptycene as well as investigations in host–guest chemistry of a triple alane with a threefold amine are reported.

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The unusual solid state structure of heroin hydrochloride monohydrate and its selective detection using NQR spectroscopy

New Journal of Chemistry ◽

10.1039/b401797h ◽

2004 ◽

Vol 28 (11) ◽

pp. 1309 ◽

Cited By ~ 11

Author(s):

Elizabeth Balchin ◽

David J. Malcolme-Lawes ◽

Michael D. Rowe ◽

John A. S. Smith ◽

Michael J. Bearpark ◽

...

Keyword(s):

Solid State ◽

Selective Detection ◽

State Structure ◽

Solid State Structure ◽

Hydrochloride Monohydrate

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The structure of [Cu(bipy)3][Cu(bipy)(ala)(ClO4)2]ClO4 � a Compound with Two Different Coordination Modes in the same Complex

Revista de Chimie ◽

10.37358/rc.08.11.2003 ◽

2008 ◽

Vol 59 (11) ◽

Author(s):

Mircea Braban ◽

Ionel Haiduc

Keyword(s):

Solid State ◽

Chelate Ring ◽

Octahedral Complex ◽

State Structure ◽

Complex Species ◽

Solid State Structure ◽

Coordination Modes ◽

Coordination Center ◽

Self Assembled ◽

Chelate Rings

The paper describes the solid state structure of a compound of composition [Cu(bipy)3][Cu(bipy)(ala) (ClO4)2]ClO4, in which both the cation and anion are octahedral complex species with copper(II) as coordination center. The cation contains three chelate rings formed by bipy; the anion contains in the quatorial plane a CuONC2 chelate ring formed by the alaninato ligand and a CuN2C2 chelate ring formed by bipy, with two monodentate perchorato ligands in axial positions completing the six-coordination. In the crystal p-p stackings lead to a supramolecular self-assembled structure.

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Synthesis and Solid-State Structure of (4-Hydroxy-3,5-diiodophenyl)phosphine Oxides. Dimeric Motifs with the Assistance of O-H···O=P Hydrogen Bonds

Current Organic Chemistry ◽

10.2174/1385272819666141231000247 ◽

2015 ◽

Vol 19 (5) ◽

pp. 469-474 ◽

Cited By ~ 13

Author(s):

Nicholas Bewick ◽

Agata Arendt ◽

Yan Li ◽

S.awomir Szafert ◽

Tadeusz Lis ◽

...

Keyword(s):

Solid State ◽

Hydrogen Bonds ◽

Phosphine Oxides ◽

State Structure ◽

Solid State Structure

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Induced Fit Docking (IFD) Study of the Solid State Structure of (2E)-1-(5- bromothiophen-2-yl)-3-[4-(dimethylamino)phenyl]prop-2-en-1-one – Fragment Based Design Approach for Human Aldose Reductase Inhibition

Letters in Drug Design & Discovery ◽

10.2174/157018012802652949 ◽

2012 ◽

Vol 9 (8) ◽

pp. 789-796

Author(s):

Suresh B. Vepuri ◽

H. C. Devarajegowda ◽

S. Anbazhagan ◽

Y. Rajendra Prasad

Keyword(s):

Solid State ◽

Aldose Reductase ◽

Design Approach ◽

State Structure ◽

Induced Fit Docking ◽

Induced Fit ◽

Solid State Structure ◽

Aldose Reductase Inhibition

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Insight into the formation of H-bonds propagating the monomeric zinc complexes of a tridentate reduced Schiff base to form an infinite chain

CrystEngComm ◽

10.1039/d0ce01840f ◽

2021 ◽

Author(s):

Mainak Karmakar ◽

Antonio Frontera ◽

Shouvik Chattopadhyay

Keyword(s):

Schiff Base ◽

Solid State ◽

Dft Calculations ◽

Zinc Complexes ◽

Infinite Chain ◽

State Structure ◽

Computational Tools ◽

Solid State Structure ◽

Reduced Schiff Base ◽

Insight Into

The formation of an infinite 1D assembly is governed by the H-bonding interactions in the solid state structure of the two zinc complexes. It has been analyzed energetically using DFT calculations and several computational tools.

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