Highly Active and Iso-Selective Catalysts for the Ring-Opening Polymerization of Cyclic Esters using Group 2 Metal Initiators

2017 ◽  
Vol 23 (39) ◽  
pp. 9319-9331 ◽  
Author(s):  
Jayeeta Bhattacharjee ◽  
Adimulam Harinath ◽  
Hari Pada Nayek ◽  
Alok Sarkar ◽  
Tarun K. Panda
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cyclic Esters ◽  
Highly Active ◽  
Group 2

Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts

2010 ◽  
Vol 82 (8) ◽  
pp. 1647-1662 ◽  
Author(s):  
Malcolm H. Chisholm
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Solvent Free ◽  
Single Site ◽  
Active Group ◽  
Cyclic Esters ◽  
Highly Active ◽  
Group 2 ◽  
Single Site Catalysts ◽  
Competing Reactions

A summary of the reactions involved in the ring-opening polymerization (ROP) of lactide (LA) to give polylactides (PLAs) is presented along with competing reactions. Particular attention is given to the stereoselective polymerization of rac-LA to give heterotactic PLA and meso-LA to give syndiotactic PLA by aluminum Schiff-based catalysts and to the development of highly active group 2 metal single-site catalysts. Melt or solvent-free polymerization is also described along with reactions that lead exclusively to cyclic-polylactides.

Ring Opening Polymerization and Copolymerization of Cyclic Esters Catalyzed by Group 2 Metal Complexes Supported by Functionalized P–N Ligands

2018 ◽  
Vol 57 (5) ◽  
pp. 2503-2516 ◽  
Author(s):  
Adimulam Harinath ◽  
Jayeeta Bhattacharjee ◽  
Alok Sarkar ◽  
Hari Pada Nayek ◽  
Tarun K. Panda
Keyword(s):  
Metal Complexes ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cyclic Esters ◽  
Group 2

A switchable dimeric yttrium complex and its three catalytic states in ring opening polymerization

2021 ◽  
Author(s):  
Shijie Deng ◽  
Paula L. Diaconescu
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Oxidation States ◽  
Cyclic Esters

A dimeric yttrium phenoxide complex can be oxidized in a stepwise fashion to access three oxidation states. The three states show different activity in the ring opening polymerization of cyclic esters and epoxides.

Sodium complexes bearing cavity-like conformations: a highly active and well-controlled catalytic system for macrolactone homo- and copolymerization

2021 ◽  
Vol 12 (13) ◽  
pp. 1957-1966
Author(s):  
Xinya Wang ◽  
Xiaohua Wang ◽  
Nuo Zhen ◽  
Jin Gu ◽  
Hao Zhang ◽  
...  
Keyword(s):  
Catalytic System ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Highly Active ◽  
Sodium Complexes

Sodium complexes displaying cavity-like conformations and, therefore, suppressed transesterification during the ring-opening polymerization of pentadecalactone are disclosed herein.

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