Size Matters: From Two‐Dimensional Au
            I
            –Tl
            I
            Metallopolymers to Molecular Complexes by Simple Variation of the Steric Demand

This paper presents a simple and effective method to fabricate water-soluble two-dimensional (2D) conductive poly(3,4-ethylenedioxythiophene):poly (sodium 4-styrenesulfonate) (PEDOT:PSS) nanosheets. Linear PSS is water-soluble and exhibits a quasi 1D structure in the dilute solution. Addition of 3,4-ethylenedioxythiophene (EDOT) monomers into acidic solutions would form 2D molecular complexes due to charge attraction. In situ polymerization of the ethylenedioxythiophene monomers produces 2D poly EDOT nanosheets. Both transmission electron microscopy and atomic force microscopy characterizations have confirmed the 2D polymeric nanosheets. Further Fourier transform infrared (FTIR) characterization also validated that the 2D nanosheet is composed of EDOT-based units and Raman spectroscopy indicated the strong interactions between ethylenedioxythiophene units in the 2D nanostructures. The electrical conductivity is measured to as high as 551.58 S/m for the thin film of as-produced 2D PEDOT:PSS nanosheets.

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Efficient tool to calculate two-dimensional optical spectra for photoactive molecular complexes

Physical Review E ◽

10.1103/physreve.92.042708 ◽

2015 ◽

Vol 92 (4) ◽

Cited By ~ 7

Author(s):

Hong-Guang Duan ◽

Arend G. Dijkstra ◽

Peter Nalbach ◽

Michael Thorwart

Keyword(s):

Molecular Complexes ◽

Optical Spectra ◽

Two Dimensional ◽

Efficient Tool

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Detection and separation of heterogeneity in molecular complexes by statistical analysis of their two-dimensional projections

Journal of Structural Biology ◽

10.1016/j.jsb.2007.11.007 ◽

2008 ◽

Vol 162 (1) ◽

pp. 108-120 ◽

Cited By ~ 59

Author(s):

Nadav Elad ◽

Daniel K. Clare ◽

Helen R. Saibil ◽

Elena V. Orlova

Keyword(s):

Statistical Analysis ◽

Molecular Complexes ◽

Two Dimensional ◽

Detection And Separation

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Two Dimensional Electronic Spectroscopy of Molecular Complexes

Journal of the Chinese Chemical Society ◽

10.1002/jccs.200600002 ◽

2006 ◽

Vol 53 (1) ◽

pp. 15-24 ◽

Cited By ~ 48

Author(s):

Minhaeng Cho ◽

Tobias Brixner ◽

Igor Stiopkin ◽

Harsha Vaswani ◽

Graham R. Fleming

Keyword(s):

Electronic Spectroscopy ◽

Molecular Complexes ◽

Two Dimensional

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Tuning the Kondo resonance in two-dimensional lattices of cerium molecular complexes

Nanoscale ◽

10.1039/c7nr08202a ◽

2018 ◽

Vol 10 (19) ◽

pp. 9123-9132

Author(s):

Julien Granet ◽

Muriel Sicot ◽

Bertrand Kierren ◽

Simon Lamare ◽

Frédéric Chérioux ◽

...

Keyword(s):

Self Assembly ◽

Kondo Effect ◽

Molecular Complexes ◽

Two Dimensional ◽

Kondo Resonance ◽

Double Decker

The Kondo effect in Ce-based double-decker molecular self-assembly can be observed or not depending on the substrate.

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Micro-scale two-dimensional electrophoresis of alkaline phosphatase from serum.

Clinical Chemistry ◽

10.1093/clinchem/34.4.730 ◽

1988 ◽

Vol 34 (4) ◽

pp. 730-735 ◽

Cited By ~ 4

Author(s):

G J Sanderink ◽

Y Artur ◽

F Paille ◽

M M Galteau ◽

G Siest

Keyword(s):

Alkaline Phosphatase ◽

Liver Microsomes ◽

Molecular Complexes ◽

Placental Alkaline Phosphatase ◽

Two Dimensional ◽

Two Dimensional Electrophoresis ◽

Micro Scale ◽

Interindividual Variations ◽

Alkaline Phosphatase Isoenzyme ◽

Dimensional Electrophoresis

Abstract Isoenzymes of alkaline phosphatase (EC 3.1.3.1) were separated by micro-scale two-dimensional electrophoresis, with isoelectric focusing in capillary gels in the first dimension and polyacrylamide gradient-gel electrophoresis in the second. The isoenzymes detected were identified by several treatments--e.g., incubation with sialidase, papain, Triton X-100, and wheat-germ agglutinin--and by comparison with alkaline phosphatase from liver microsomes. Liver and bone isoforms in normal sera showed overlapping isoelectric points but differed in molecular mass, estimated as 172 and 185 kDa, respectively. Sera of patients with liver disease showed several additional groups of alkaline phosphatase isoforms, two of which were found to consist of multi-molecular complexes. Others probably correspond to incompletely glycated enzyme proteins. A further isoform with a mass of about 250 kDa does not seem to correspond to any known isoform of alkaline phosphatase in serum. With this technique, we demonstrated intra- and interindividual variations of the placental alkaline phosphatase isoenzyme in pregnancy sera.

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