Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C‐F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver

2021 ◽  
Author(s):  
Zhifang Guo ◽  
Victoria L. Blair ◽  
Glen B. Deacon ◽  
Peter C. Junk
Keyword(s):  
Oxidation State ◽  
Ligand Effects

Quantifying ligand effects in high-oxidation-state metal catalysis

2017 ◽  
Vol 9 (9) ◽  
pp. 837-842 ◽  
Author(s):  
Brennan S. Billow ◽  
Tanner J. McDaniel ◽  
Aaron L. Odom
Keyword(s):  
Oxidation State ◽  
High Oxidation State ◽  
Metal Catalysis ◽  
Ligand Effects ◽  
High Oxidation

Ligand Effects in Bimetallic High Oxidation State Palladium Systems

2010 ◽  
Vol 49 (23) ◽  
pp. 11249-11253 ◽  
Author(s):  
Alireza Ariafard ◽  
Christopher J. T. Hyland ◽  
Allan J. Canty ◽  
Manab Sharma ◽  
Nigel J. Brookes ◽  
...  
Keyword(s):  
Oxidation State ◽  
High Oxidation State ◽  
Ligand Effects ◽  
High Oxidation

Non-Innocent Ligand Effects on Low-Oxidation-State Indium Complexes

2013 ◽  
Vol 19 (43) ◽  
pp. 14470-14483 ◽  
Author(s):  
Christopher J. Allan ◽  
Benjamin F. T. Cooper ◽  
Hugh J. Cowley ◽  
Jeremy M. Rawson ◽  
Charles L. B. Macdonald
Keyword(s):  
Oxidation State ◽  
Indium Complexes ◽  
Ligand Effects ◽  
Low Oxidation State

Organometallic model complexes elucidate the active gallium species in alkane dehydrogenation catalysts based on ligand effects in Ga K-edge XANES

2016 ◽  
Vol 6 (16) ◽  
pp. 6339-6353 ◽  
Author(s):  
Andrew “Bean” Getsoian ◽  
Ujjal Das ◽  
Jeffrey Camacho-Bunquin ◽  
Guanghui Zhang ◽  
James R. Gallagher ◽  
...  
Keyword(s):  
Oxidation State ◽  
Model Compounds ◽  
Model Complexes ◽  
Alkane Dehydrogenation ◽  
Ligand Effects

Ga(iii)-alkyl and alkoxide model compounds demonstrate XANES edge energy shifts similar to those in Ga dehydrogenation catalysts without a change in Ga oxidation state.

Chromium oxidation state mapping in human cells

2003 ◽  
Vol 104 ◽  
pp. 289-292 ◽  
Author(s):  
R. Ortega ◽  
B. Fayard ◽  
M. Salomé ◽  
G. Devès ◽  
J. Susini
Keyword(s):  
Oxidation State ◽  
Human Cells ◽  
Chromium Oxidation

A Short Synthesis of (+)-Brefeldin C via Enantioselective Radical Hydroalkynylation

2019 ◽  
Author(s):  
Lars Gnägi ◽  
Severin Vital Martz ◽  
Daniel Meyer ◽  
Robin Marc Schärer ◽  
Philippe Renaud
Keyword(s):  
Total Synthesis ◽  
Natural Product ◽  
Oxidation State ◽  
Single Step ◽  
Radical Process ◽  
Target Molecule ◽  
Short Synthesis ◽  
The One

<div><div><div><div><p>A very concise total synthesis of (+)-brefeldin C starting from 2-furanylcyclopentene is described. This approach is based on an unprecedented enantioselective radical hydroalkynylation process to introduce the two cyclopentane stereocenters in a single step. The use of a furan substituent allows to achieve a high trans diastereoselectivity during the radical process and it contains the four carbon atoms C1–C4 of the natural product in an oxidation state closely related to the one of the target molecule. The eight-step synthesis require six product purifications and it provides (+)-brefeldin C in 18% overall yield.</p></div></div></div></div>

Determination of interdependent ligand effects on human red cell oxygen affinity

1982 ◽  
Vol 42 (4) ◽  
pp. 339-345
Author(s):  
W. G. Zijlstra ◽  
B. Oeseburg ◽  
G. Kwant ◽  
A. Zwart
Keyword(s):  
Oxygen Affinity ◽  
Red Cell ◽  
Ligand Effects
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