d‐Orbital Reconstructions Forced by Double Bow‐Shaped Deformations and Second Coordination Sphere Effects of Cu(II) Heme Analogs in HER**

2022 ◽  
Author(s):  
Qiuhua Liu ◽  
Wanjie Ren ◽  
Siwei Zhang ◽  
Yang Huang ◽  
Dilong Chen ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Second Coordination Sphere

scholarly journals Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures

2020 ◽  
Vol 49 (8) ◽  
pp. 2381-2396 ◽  
Author(s):  
Philipp Gotico ◽  
Zakaria Halime ◽  
Ally Aukauloo
Keyword(s):  
Carbon Dioxide ◽  
Coordination Sphere ◽  
Three Dimensional ◽  
Carbon Dioxide Reduction ◽  
Catalyst Design ◽  
Recent Advances ◽  
Hierarchical Architectures ◽  
Second Coordination Sphere

The progress in CO2 reduction catalyst design was examined starting from simple metalloporphyrin structures and progressing to three-dimensional active architectures.

scholarly journals An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential

2021 ◽  
Vol 12 (13) ◽  
pp. 4779-4788
Author(s):  
Yong Yang ◽  
Mehmed Z. Ertem ◽  
Lele Duan
Keyword(s):  
Coordination Sphere ◽  
Bond Cleavage ◽  
Low Overpotential ◽  
Second Coordination Sphere ◽  
Co Reduction ◽  
Reduction Catalysts

The amide NH group decreases the overpotential of Mn-based CO2 reduction catalysts by promoting the dimer and protonation-first pathways in the presence of H2O and enhances the CO2 electroreduction activity by facilitating C–OH bond cleavage.

scholarly journals Selective Formation of an FeIV O or an FeIII OOH Intermediate From Iron(II) and H2 O2 : Controlled Heterolytic versus Homolytic Oxygen-Oxygen Bond Cleavage by the Second Coordination Sphere

2018 ◽  
Vol 131 (3) ◽  
pp. 864-868 ◽  
Author(s):  
Khaled Cheaib ◽  
M. Qadri E. Mubarak ◽  
Katell Sénéchal-David ◽  
Christian Herrero ◽  
Régis Guillot ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Bond Cleavage ◽  
Oxygen Oxygen ◽  
Second Coordination Sphere ◽  
Selective Formation ◽  
Oxygen Bond

scholarly journals Second-Coordination-Sphere Assisted Selective Colorimetric Turn-on Fluoride Sensing by a Mono-Metallic Co(II) Hexacarboxamide Cryptand Complex

2017 ◽  
Vol 56 (14) ◽  
pp. 7615-7619 ◽  
Author(s):  
Julia M. Stauber ◽  
Glen E. Alliger ◽  
Daniel G. Nocera ◽  
Christopher C. Cummins
Keyword(s):  
Coordination Sphere ◽  
Turn On ◽  
Second Coordination Sphere ◽  
Fluoride Sensing
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