ChemInform Abstract: THE SYNTHESIS AND PYROLYTIC REARRANGEMENT OF PHTHALATE ESTERS OF SOME TERTIARY SILANOLS, AN ATTEMPT TO PREPARE A SILICON CARBON DOUBLE BOND SPECIES

1975 ◽  
Vol 6 (17) ◽  
pp. no-no
Author(s):  
K. G. RUTHERFORD ◽  
R. J. SEIDEWAND
Keyword(s):  
Double Bond ◽  
Phthalate Esters ◽  
Carbon Double Bond ◽  
Silicon Carbon

The Synthesis and Pyrolytic Rearrangement of Phthalate Esters of Some Tertiary Silanols. An Attempt to Prepare a Silicon Carbon Double Bond Species

1975 ◽  
Vol 53 (1) ◽  
pp. 67-70 ◽  
Author(s):  
K. G. Rutherford ◽  
R. J. Seidewand
Keyword(s):  
Double Bond ◽  
Carbon Atom ◽  
Phthalic Anhydride ◽  
Phthalate Esters ◽  
Optically Active ◽  
Asymmetric Carbon Atom ◽  
Silyl Ethers ◽  
Carbon Double Bond ◽  
Silicon Carbon ◽  
Asymmetric Carbon

The synthesis and pyrolysis of the methyl phthalate esters of diphenylmethylsilyl, t-butylsilyl, benzyldiphenylsilyl, and optically active 2-octanol yielded corresponding silyl ethers and phthalic anhydride. In the case of the latter compound, almost complete retention of configuration was observed about the asymmetric carbon atom. A mechanism is proposed for this rearrangement.

Formation of an unstable silicon-carbon double bond in the photodecomposition of trimethylsilyldiazoacetate

1973 ◽  
Vol 95 (22) ◽  
pp. 7518-7519 ◽  
Author(s):  
Wataru. Ando ◽  
Tsuneo. Hagiwara ◽  
Toshihiko. Migita
Keyword(s):  
Double Bond ◽  
Carbon Double Bond ◽  
Silicon Carbon
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