ChemInform Abstract: SOLID SOLUTIONS IN THE AMMONIUM PEROXYDISULFATE-POTASSIUM PEROXYDISULFATE AND AMMONIUM SULFATE-POTASSIUM SULFATE SYSTEMS COEXISTING WITH SATURATED AQUEOUS SOLUTIONS

1977 ◽  
Vol 8 (2) ◽  
pp. no-no
Author(s):  
J. BALEJ
Keyword(s):  
Aqueous Solutions ◽  
Ammonium Sulfate ◽  
Solid Solutions ◽  
Potassium Sulfate ◽  
Ammonium Peroxydisulfate ◽  
Potassium Peroxydisulfate

Simulation of the nucleation and growth of binary solid solutions in aqueous solutions

2010 ◽  
Vol 269 (1-2) ◽  
pp. 89-99 ◽  
Author(s):  
C. Noguera ◽  
B. Fritz ◽  
A. Clément ◽  
Y. Amal
Keyword(s):  
Aqueous Solutions ◽  
Solid Solutions ◽  
Nucleation And Growth

Concentration Oscillations During Diffusion With Slow First-Order Chemical Reaction in Aqueous Solutions of trans-Dichloro-bis(ethane-1,2-diamine)cobalt(III) Chloride, trans-[Co(en)2Cl2]Cl

1988 ◽  
Vol 41 (4) ◽  
pp. 469 ◽  
Author(s):  
DG Leaist
Keyword(s):  
Aqueous Solutions ◽  
Chemical Reaction ◽  
Diffusion Coefficients ◽  
Potassium Acetate ◽  
Potassium Sulfate ◽  
Rate Equations ◽  
Ternary Diffusion ◽  
Mixed Electrolyte ◽  
First Order ◽  
First Order Chemical Reaction

The rate equations for diffusion and chemical reaction have been solved for isothermal diffusion with the first-order reactionA → Bin stirred diaphragm cells. Provided pseudo-steady-state conditions are established in the diaphragms, the concentration differences across the diaphragm for the reactant and product are predicted to show damped oscillations in time for certain values of the solute diffusivities. Diffusion coefficients have been determined for aqueous solutions of trans-dichlorobis (ethane-1,2-diamine)cobalt(III) chloride in which the 1 : 1 salt slowly converts into a 1:2 salt through the reaction [Co(en)2Cl2]+ + Cl - → [Co(en)2Cl]2+ +2Cl- with k = 3.6×10-5 s-1 at 25°C. Supplementary ternary diffusion coefficients have been determined for aqueous solutions of potassium acetate + potassium sulfate, a ternary mixed electrolyte with ionic mobilities similar to those of the aqueous cobalt salts.

Crystallization of PbxSr1-x(NO3)2 Solid Solutions from Aqueous Solutions

2000 ◽  
Vol 35 (5) ◽  
pp. 601-608 ◽  
Author(s):  
L.J. Wu ◽  
W.C. Chen ◽  
C.R. Li ◽  
Y.C. Liu ◽  
W.Y. Ma ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Solid Solutions
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